In systems undergoing localization-delocalization quantum phase transitions due to disorder or monitoring, there is a crucial need for robust methods capable of distinguishing phases and uncovering their intrinsic properties. In this paper, we develop a process of finding a Slater determinant representation of free-fermion wave functions that accurately characterizes localized particles, a procedure we dub "unscrambling." The central idea is to minimize the overlap between envelopes of single-particle wave functions or, equivalently, to maximize the inverse participation ratio of each orbital. This numerically efficient methodology can differentiate between distinct types of wave functions: exponentially localized, power-law localized, and conformal critical, also revealing the underlying physics of these states. The method is readily extendable to systems in higher dimensions. Furthermore, we apply this approach to a more challenging problem involving disordered monitored free fermions in one dimension, where the unscrambling process unveils the presence of a conformal critical phase and a localized area-law quantum Zeno phase. Importantly, our method can also be extended to free fermion systems without particle number conservation, which we demonstrate by estimating the phase diagram of Z2-symmetric disordered monitored free fermions. Our results unlock the potential of utilizing single-particle wave functions to gain valuable insights into the localization transition properties in systems such as monitored free fermions and disordered models.