Synthesis and study of structural and electrophysical characteristics of piezoceramic section (1-x)(0.8PbMg1/3Nb2/3O3⋅0.2BiScO3)⋅ x(0.8PbTiO3⋅0.2BiScO3) of the ternary system BiScO3-PbTiO3-PbMg1/3Nb2/3O3

被引:0
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作者
Nogai, Artur [1 ]
Sysoev, Maxim [2 ]
Bush, Alexandr [2 ]
Nogai, Adolf [1 ]
机构
[1] S Seifullin Kazakh Agrotech Res Univ, Dept Radio Engn Elect & Telecommun, Zhenis Ave 62, Astana 010011, Kazakhstan
[2] Russian Technol Univ, Inst Adv Technol & Ind Programming MIREA, Dept Nanoelect, Vernadsky Ave 78, Moscow 119454, Russia
关键词
Piezoceramics; dielectric properties; structure; morphotropic phase boundary; ferroelectrics; relaxor ferroelectrics; PHASE-DIAGRAM; FERROELECTRICS; POROSITY;
D O I
10.1142/S2010135X24500115
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
X-ray diffraction and dielectric studies were performed on synthesized ceramic samples of the section (1-x) (0.8PbMg(1/3)Nb(2/3)O(3)& sdot;0.2BiScO(3))& sdot; x(0.8PbTiO(3)& sdot;0.2BiScO(3)) with x=0-1 of the ternary BiScO3-PbTiO3-PbMg1/3Nb2/3O3 (BS-PT-PMN) system, including the temperature dependence of thermally stimulated depolarization currents (TSDC). It was found that the samples are solid solutions with a perovskite structure, which have cubic symmetry in the range of x = 0-0.587 and tetragonal symmetry in the range of x = 0.680-1. In the intermediate composition range of x = 0.587-0.680 (morphotropic region - MR), the samples consist of a mixture of solid solutions of different symmetries. Data on the change in dielectric properties and TSDC(T) dependencies of solid solutions with a change in their composition were obtained. It was found that samples of compositions x =0-0.625 and 0.6875-1 exhibit relaxor-ferroelectric and conventional ferroelectric properties, respectively, while samples of compositions x = 0.625-0.6875 combine ferroelectric and relaxor-ferroelectric properties.
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页数:6
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