Densities and excess volumes of binary and ternary mixtures of N, N-dimethyl sulfoxide, N,N-dimethylacetamide, and N-methyl-2-pyrrolidone at T = (293.15, 313.15)K and atmospheric pressure

被引:5
|
作者
Zhuchkov, Valeriy [1 ]
Raeva, Valentina [1 ]
Frolkova, Alla [1 ]
机构
[1] Russian Technol Univ, Dept Chem & Technol Basic Organ Synth, MIREA, 78 Vernadsky Avenu, Moscow, Russia
来源
CHEMICAL DATA COLLECTIONS | 2022年 / 38卷
关键词
Densities; Excess volumes; N N-Dimethyl acetamide (DMA); Dimethyl sulfoxide (DMSO); N-Methyl-2-pyrrolidone (NMP); VAPOR-LIQUID-EQUILIBRIUM; EXTRACTIVE DISTILLATION PROCESS; PLUS WATER MIXTURES; REFRACTIVE-INDEX; MOLECULAR-INTERACTIONS; ISOTHERMAL COMPRESSIBILITIES; ISENTROPIC COMPRESSIBILITIES; MIXED ENTRAINER; 20; MPA; VISCOSITY;
D O I
10.1016/j.cdc.2022.100840
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities of binary liquid mixtures of N,N-dimethyl acetamide (DMA) + dimethyl sulfoxide (DMSO), DMSO + N - methyl-2-pyrrolidone (NMP), and DMA + NMP were measured over the entire composition range in the temperatures of 293.15 K and 313.15 K at atmospheric pressure. Based on this measurements, density deviations, Delta rho, and excess molar volumes, V-E , of binary mixtures were calculated and the same were fitted by Redlich-Kister equation. Binary adjustable parameters were obtained using Linear Least Squares Regression (Microsoft Excel 2016). The variations of derivative properties with temperature and composition were discussed. The densities of ternary mixtures DMSO + DMA + NMP were measured at 293.15 K and 313.15 K. According to experimental data, diagrams of density isolines at both temperature, density changes and excess molar volume at 293.15 K are constructed.
引用
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页数:14
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