Celecoxib Catalyzed the Coupling Reaction of Epoxide and CO2

被引:0
作者
Wu, Ling [1 ]
Xia, Xiaocheng [1 ]
An, Wenying [1 ]
Cui, Wenshan [1 ]
Liu, Yue [1 ]
Lv, Wei [1 ]
Wu, Fengtian [1 ]
机构
[1] East China Univ Technol, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Devi, Nanchang 330013, Peoples R China
关键词
Carbon dioxide; epoxide; cyclic carbonate; TBAB; celecoxib; benzoic acid; CARBON-DIOXIDE; CYCLIC CARBONATES; ORGANOCATALYSTS; CONVERSION;
D O I
10.2174/0115701786276731231206113215
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this study, high yields of various cyclic carbonates are obtained by employing the drug celecoxib to promote the coupling reaction of CO2 and epoxide using tetrabutylammonium bromide. This strategy enables the synthesis of benzoic acid, phenylpropiolic acid, and 2, 4-quinazolinedione. In addition, the model reaction mechanism is proposed.
引用
收藏
页码:611 / 619
页数:9
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