MnO2 superstructure cathode with boosted zinc ion intercalation for aqueous zinc ion batteries

被引:14
作者
Zhang, Aina [1 ]
Zhang, Xu [1 ]
Zhao, Hainan [1 ,2 ]
Ehrenberg, Helmut [2 ]
Chen, Gang [1 ]
Saadoune, Ismael [3 ]
Fu, Qiang [2 ]
Wei, Yingjin [1 ]
Wang, Yizhan [1 ]
机构
[1] Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Batteries, Minist Educ, Changchun 130012, Peoples R China
[2] Karlsruhe Inst Technol, Inst Appl Mat, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[3] Mohammed VI Polytech Univ UM6P, Lot 660 Hay Moulay Rachid, Benguerir 43150, Morocco
基金
中国国家自然科学基金;
关键词
Aqueous zinc ion batteries; MnO2; Superstructure; In operando synchrotron diffraction; X-ray absorption spectroscopy; PERFORMANCE; ALPHA-MNO2; NANOSHEETS; MECHANISM; STORAGE; OXIDE; H+;
D O I
10.1016/j.jcis.2024.05.052
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The simultaneous intercalation of protons and Zn2+ ions in aqueous electrolytes presents a significant obstacle to the widespread adoption of aqueous zinc ion batteries (AZIBs) for large-scale use, a challenge that has yet to be overcome. To address this, we have developed a MnO2/tetramethylammonium (TMA) superstructure with an enlarged interlayer spacing, designed specifically to control H+/Zn2+ co-intercalation in AZIBs. Within this superstructure, the pre-intercalated TMA+ ions work as spacers to stabilize the layered structure of MnO2 cathodes and expand the interlayer spacing substantially by 28 % to 0.92 nm. Evidence from in operando pH measurements, in operando synchrotron X-ray diffraction, and X-ray absorption spectroscopy shows that the enlarged interlayer spacing facilitates the diffusion and intercalation of Zn2+ ions (which have a large ionic radius) into the MnO2 cathodes. This spacing also helps suppress the competing H+ intercalation and the formation of detrimental Zn4(OH)6SO4 & sdot;5H2O, thereby enhancing the structural stability of MnO2. As a result, enhanced Zn2+ storage properties, including excellent capacity and long cycle stability, are achieved.
引用
收藏
页码:723 / 730
页数:8
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