MnO 2 enhanced low temperature HCHO sensing performance of SnO 2

被引:16
作者
Fan, Guijun [1 ,2 ,3 ]
Huo, Feng [4 ]
Guan, Jian [1 ,2 ,3 ]
Yu, Hang [1 ,2 ,3 ]
Zhu, Qiuyi [1 ,2 ,3 ]
Han, Ning [1 ,2 ,3 ]
Mo, Jinhan [5 ]
Chen, Yunfa [1 ,2 ,3 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Inst Proc Engn, Key Lab Sci & Technol Particle Mat, Beijing 100190, Peoples R China
[4] Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[5] Shenzhen Univ, Coll Civil & Transportat Engn, Shenzhen 518060, Peoples R China
关键词
Gas sensor; Formaldehyde; SnO2/MnO2; In-situ DRIFTS; Sensing mechanism; FORMALDEHYDE DETECTION; FACILE SYNTHESIS; GAS SENSOR; MECHANISM; COMPOSITES; GROWTH; ARRAY; NOX;
D O I
10.1016/j.snb.2024.135803
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The exploration of gas sensing materials holds significant importance for practical applications. This work introduces a novel SnO2/MnO2 nanocomposite designed to achieve formaldehyde monitoring at ppb level with a relative low temperature. The as prepared sensor demonstrates a response of 8.1-50 ppb formaldehyde at 100 degrees C. These remarkable formaldehyde sensing capabilities were explained by the heterojunction structure of the composite, and the low-temperature catalytic properties of MnO2. Moreover, in-situ infrared reflectance spectroscopy was employed to investigate the underlying mechanism by monitoring the evolution of reaction intermediates, and the result suggested that the addition of MnO2 can reduce the ineffective occupation of active sites and promote the generation of intermediate intermediates.
引用
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页数:8
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