Tribology of 2D black phosphorus - Current state-of-the-art and future potential

被引:10
作者
Boidi, Guido [1 ]
Ronai, Bettina [1 ]
Heift, Dominikus [2 ]
Benini, Francesca [3 ]
Varga, Markus [1 ]
Righi, Maria Clelia [3 ]
Rosenkranz, Andreas [4 ]
机构
[1] AC2T Res GmbH, Viktor Kaplan Str 2-C, A-2700 Wiener Neustadt, Austria
[2] Kingston Univ, Sch Life Sci Pharm & Chem, Penrhyn Rd, Kingston Upon Thames KT1 2EE, England
[3] Univ Bologna, Dept Phys & Astron Augusto Righi, I-40127 Bologna, Italy
[4] Univ Chile, Dept Chem Engn Biotechnol & Mat, FCFM, Santiago 8370415, Chile
关键词
2D materials; Black phosphorus; Tribology; Friction; Wear; Tribofilm; MACROSCALE SUPERLUBRICITY; 2-DIMENSIONAL MATERIALS; ELASTIC PROPERTIES; GROWTH-MECHANISM; RED PHOSPHORUS; MOS2; CRYSTAL; WATER; GRAPHENE; OPTOELECTRONICS;
D O I
10.1016/j.cis.2024.103180
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Since the first mechanical exfoliation of graphene in 2004, the interest in 2D materials has significantly risen due to their outstanding property combination. Multiple 2D materials have been synthesized until today, while black phosphorus (BP) resembles one of their latest additions. The unique properties of BP, especially for electronic and optical devices ( i.e. , high carrier mobility and electrical conduction, field-effect transistor, layer -dependent bandgap, anisotropic transport), have gained notable attention. However, its layered structure, similar to those of graphene and MoS 2 , is also advantageous to optimize the friction and wear performance. Moreover, the strong in -plane covalent bonds and weak interlayer van-der-Waals forces favour the formation of low -friction and wear -resistant films. Although BP holds a great tribological potential, the literature to date on this topic is rather scarce. Therefore, it is a timely moment to holistically summarize the synthesis approaches and properties of BP thus guiding interested researchers to use it in mechanical/tribological applications. The existing state-of-the-art regarding tribological research is critically discussed and compared to other 2D materials thus highlighting existing research gaps and paving the way for future research activities.
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页数:15
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