Two new Zn(ii) coordination polymers incorporating 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline: Synthesis and structure

被引：4

作者：

Wang, Huilin ^{[1
,2
]}

Wang, Xin ^{[2
]}

Li, Meimiao ^{[2
]}

Feng, Jingdong ^{[1
,2
]}

机构：

[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Changchun 130103, Peoples R China

[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China

来源：

MAIN GROUP METAL CHEMISTRY | 2024年 / 47卷 / 01期

关键词：

coordination polymer; Zn(II); phenanthroline derivatives; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE DETERMINATION; CONSTRUCTION; ADSORPTION; LIGAND; CARBON;

D O I：

10.1515/mgmc-2023-0033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Based on phenanthroline derivate ligand and Zn(ii), two novel coordination polymers, namely [Zn(L)(hta)](n) (1) and {[Zn-2(L)(2)(dhb)(2)]<middle dot>H2O}(n) (2) (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, H(2)hta = heptanedioic acid, and H(2)dhb = 3,5-dinitro-2-hydroxybenzoic acid), have been synthesized under the hydrothermal condition. For 1, each hta anion bridges two Zn(ii) atoms in a tridentate mode to shape into a chain structure and through different pi-pi stacking interactions to form a three-dimensional supramolecular structure. The L ligand of 2 connects two neighbouring Zn(ii) atoms to give a 1D chain, which is further extended into the 2D supramolecular layer.

引用

页数：6

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