Carbonylative transformations with Pd catalysts supported on bio-degradable urea-based polymer - Part A

被引：1

作者：

Markovic, Martin ^{[1
,3
]}

Lopatka, Pavol ^{[2
]}

Koos, Peter ^{[1
,3
]}

Sotak, Tomas ^{[2
]}

Haz, Ales ^{[4
]}

Gracza, Tibor ^{[1
]}

Ley, Steven V. ^{[5
]}

Kralik, Milan ^{[2
]}

机构：

[1] Slovak Univ Technol Bratislava, Inst Organ Chem Catalysis & Petrochem, Dept Organ Chem, Radlinskeho 9, SK-81237 Bratislava, Slovakia

[2] Slovak Univ Technol Bratislava, Inst Organ Chem Catalysis & Petrochem, Dept Organ Technol Catalysis & Petr Chem, SK-81237 Bratislava, Slovakia

[3] Georganics Ltd, Korenicova 1, SK-81103 Bratislava, Slovakia

[4] Slovak Univ Technol Bratislava, Inst Nat & Synthet Polymers, Dept Wood Pulp & Paper, SK-81237 Bratislava, Slovakia

[5] Univ Cambridge, Yusuf Hamied Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England

来源：

CATALYSIS TODAY | 2024年 / 441卷

关键词：

Aminocarbonylation; Urea polymer; Palladium; Degradation; PALLADIUM NANOPARTICLES; ARYL IODIDES; AMINOCARBONYLATION; HYDROGENATION; CO; CADAVERINE; EFFICIENT;

D O I：

10.1016/j.cattod.2024.114903

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Herein, we present the development of a novel palladium catalyst supported on a urea-based polymer and its application in aminocarbonylation employing FeBr2(CO)4 as a CO source. The polymer support for Pd metal is derived from naturally occurring biogenic cadaverine scaffold, which has been partially modified with picolyl amine. The synthetic approach developed for the preparation of urea-based support enables targeted modification of the ligand component of the polymer support for improved metal binding. The Pd@UBPS catalyst demonstrates high activity and good stability in the aminocarbonylation reaction affording a range of carboxamide products.

引用

页数：14

共 13 条

[1] Development of bio-degradable based polymer electrolytes for EDLC application
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Sundari, G. Sunita
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OPTIK, 2021, 241
[2] Palladium catalysts supported on biodegradable urea-based polymers in synthesis with CO - Part B
Markovic, Martin
Lopatka, Pavol
Koos, Peter
Sotak, Tomas
Haz, Ales
Gracza, Tibor
Ley, Steven V.
Kralik, Milan
CATALYSIS TODAY, 2024, 440
[3] Advances in Bio-degradable Polymer Composites-Based Packaging Material
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[4] Advances in Bio-degradable Polymer Composites-Based Packaging Material
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[5] Lithium ion conducting solid polymer blend electrolyte based on bio-degradable polymers
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[6] Lithium ion conducting solid polymer blend electrolyte based on bio-degradable polymers
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[8] Synthesis and Characterization of Polymer Blend Electrolyte Based on Bio-degradable Polymers Doped with Ammonium Iodide
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[10] Strong, tough and bio-degradable polymer-based 3D-ink for fused filament fabrication (FFF) using WS2 nanotubes
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