Rare-earth UiO-66 for temperature sensing near room temperature

被引：9
作者：
Djanffar, Elias [1 ]
Bicalho, Hudson A. [2 ,3 ,4 ]
Ajoyan, Zvart [2 ,3 ,4 ]
Howarth, Ashlee J. [2 ,3 ,4 ]
Serier-Brault, Helene [1 ]
机构：
[1] Nantes Univ, Inst Mat Nantes Jean Rouxel, CNRS, IMN, F-44000 Nantes, France
[2] Concordia Univ, Dept Chem & Biochem, 7141 Sherbrooke St West, Montreal, PQ H4B 1R6, Canada
[3] Concordia Univ, Ctr Nanosci Res, 7141 Sherbrooke St West, Montreal, PQ H4B 1R6, Canada
[4] FRQNT Quebec Ctr Adv Mat QCAM CQMF, Montreal, PQ, Canada
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2024年 / 12卷 / 22期
关键词：
METAL-ORGANIC FRAMEWORK; THERMOMETER; REMOVAL; DESIGN;
D O I：
10.1039/d4tc00781f
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In the last decade, rare-earth metal-organic frameworks (RE-MOFs) have received notable interest in luminescence thermometry, which involves correlating the absolute temperature of an object to an optical emission. Numerous investigations that are already reported deal mainly with mixed Eu/Tb coordination polymers and MOFs, and they are based on the Eu3+-to-Tb3+ emission ratio between the transitions 5D4 -> 7F5 and 5D0 -> 7F2 of the Tb3+ and Eu3+ ions, respectively. In this study, we focus our attention on the well-known UiO-66, which can be also built with lanthanoid cations to give RE-UiO-66 analogues. Thus, we investigated the thermometric properties of RE-UiO-66 by synthesizing three different bimetallic Eu/Tb materials, with the aim to develop new sensitive luminescent thermometers. Eu-Tb-UiO-66 acts as a highly sensitive luminescent thermometer near room temperature.
引用
收藏
页码：8024 / 8029
页数：6
相关论文
共 44 条
[1]   Tuning the rare-earth UiO-66 metal-organic framework platform for white light emission [J].
Ajoyan, Zvart ;
Bicalho, Hudson A. ;
Donnarumma, P. Rafael ;
Antanovich, Artsiom J. ;
Howarth, Ashlee .
JOURNAL OF MATERIALS CHEMISTRY C, 2023, 11 (26) :8929-8934
[2]   Metal-organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents [J].
Bobbitt, N. Scott ;
Mendonca, Matthew L. ;
Howarth, Ashlee J. ;
Islamoglu, Timur ;
Hupp, Joseph T. ;
Farha, Omar K. ;
Snurr, Randall Q. .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (11) :3357-3385
[3]   Alkaline-earth metal based MOFs with second scale long-lasting phosphor behavior [J].
Briones, David ;
Leo, Pedro ;
Cepeda, Javier ;
Orcajo, Gisela ;
Calleja, Guillermo ;
Sanz, Raul ;
Rodriguez-Dieguez, Antonio ;
Martinez, Fernando .
CRYSTENGCOMM, 2018, 20 (33) :4793-4803
[4]  
Brites CDS, 2016, HBK PHYS CHEM RARE, V49, P339, DOI 10.1016/bs.hpcre.2016.03.005
[5]   Thermometry at the nanoscale [J].
Brites, Carlos D. S. ;
Lima, Patricia P. ;
Silva, Nuno J. O. ;
Millan, Angel ;
Amaral, Vitor S. ;
Palacio, Fernando ;
Carlos, Luis D. .
NANOSCALE, 2012, 4 (16) :4799-4829
[6]   Lanthanide-based luminescent molecular thermometers [J].
Brites, Carlos D. S. ;
Lima, Patricia P. ;
Silva, Nuno J. O. ;
Millan, Angel ;
Amaral, Vitor S. ;
Palacio, Fernando ;
Carlos, Luis D. .
NEW JOURNAL OF CHEMISTRY, 2011, 35 (06) :1177-1183
[7]   A Luminescent Molecular Thermometer for Long-Term Absolute Temperature Measurements at the Nanoscale [J].
Brites, Carlos D. S. ;
Lima, Patricia P. ;
Silva, Nuno J. O. ;
Millan, Angel ;
Amaral, Vitor S. ;
Palacio, Fernando ;
Carlos, Luis D. .
ADVANCED MATERIALS, 2010, 22 (40) :4499-4504
[8]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[9]   Strategy design for ratiometric luminescence thermometry: circumventing the limitation of thermally coupled levels [J].
Cheng, Yao ;
Gao, Yan ;
Lin, Hang ;
Huang, Feng ;
Wang, Yuansheng .
JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (28) :7462-7478
[10]   Metal-organic frameworks for luminescence thermometry [J].
Cui, Yuanjing ;
Zhu, Fengliang ;
Chen, Banglin ;
Qian, Guodong .
CHEMICAL COMMUNICATIONS, 2015, 51 (35) :7420-7431
12345