Graphene for switchable flexible smart windows application

被引:1
作者
Bakacak, Pinar Koc [1 ]
Kovalska, Evgeniya [2 ]
Tuzemen, Sebahattin [3 ]
机构
[1] Sakarya Univ Appl Sci, Maritime Higher Vocat Sch, TR-54800 Sakarya, Turkiye
[2] Univ Exeter, Fac Environm Sci & Econ, Dept Engn, Exeter EX4 4QF, England
[3] Ataturk Univ, Fac Sci, Dept Phys, TR-25240 Erzurum, Turkiye
关键词
Graphene; Smart windows; Electrochromic device; Intercalation; Electro-optic; LAYER; SPECTROSCOPY; EFFICIENT; GRAPHITE; QUALITY;
D O I
10.1016/j.optmat.2024.115302
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Here, we designed a flexible, high-performance, foldable, and very simple -to -design electrochromic device (ECD) by using wide-area multi-layer graphene (MLG) as an electrode. ML-graphene samples were synthesized by chemical vapor deposition method (CVD); Electrical, optical, and structural characterization was performed. Following this, MLG films were transferred onto polyethylene using the water bath method, which is a very cheap and simple transfer method, and the electrochromic device design was carried out. As a result of optical measurements, it was seen that the optical transmittance value increased starting from the threshold voltage of 2.8 V and there was a change of approximately 40 % at 5 V. When the Raman spectrum of ML-graphene samples is examined, there is a distinct G peak at 1567 cm - 1 and the band position shifts to lower energy levels depending on the increasing number of layers. According to the data obtained from X-ray diffraction (XRD) spectroscopy used for structural characterization, it was concluded that p-type doping is easier than n-type and occurs at lower voltage values. Additionally, in the switching time analysis, it is seen that the time taken for the intercalation process is longer than the time for the deintercalation process.
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页数:7
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共 43 条
[1]   Fabrication of Nickel-Doped Tungsten Trioxide Thin Film-Based Highly Stable Flexible Electrochromic Devices for Smart Window Applications [J].
Ahmad, Khursheed ;
Kim, Haekyoung .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (29) :10746-10754
[2]   Preparation of CoS2/WO3 thin films for the construction of electrochromic devices [J].
Ahmad, Khursheed ;
Shinde, Mahesh A. ;
Song, Gihwan ;
Kim, Haekyoung .
CERAMICS INTERNATIONAL, 2023, 49 (06) :10119-10128
[3]  
Ahmad Khursheed, Fabrication of MoSe 2/AgNWs/PET Electrode for Flexible Electrochromic Smart Window Applications
[4]   Introduction, production, characterization and applications of defects in graphene [J].
Ahmad, Waqas ;
Ullah, Zaka ;
Sonil, Nazmina Imrose ;
Khan, Karim .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (15) :19991-20030
[5]   Photoluminescence and structural properties of zirconium dioxide thin films produced by RF sputtering technique [J].
Bakacak, Pinar K. ;
Gur, Emre ;
Bayram, Ozkan ;
Tuzemen, Sebahattin ;
Simsek, Onder .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (06) :7541-7549
[6]   New practical device structure for graphen-based electrochromic devices [J].
Bakacak, Pinar Koc ;
Tuzemen, Sebahattin ;
Kocabas, Coskun .
OPTICAL MATERIALS, 2021, 122
[7]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[8]   Approaching the limits of transparency and conductivity in graphitic materials through lithium intercalation [J].
Bao, Wenzhong ;
Wan, Jiayu ;
Han, Xiaogang ;
Cai, Xinghan ;
Zhu, Hongli ;
Kim, Dohun ;
Ma, Dakang ;
Xu, Yunlu ;
Munday, Jeremy N. ;
Drew, H. Dennis ;
Fuhrer, Michael S. ;
Hu, Liangbing .
NATURE COMMUNICATIONS, 2014, 5
[9]   Dispersible composites of exfoliated graphite and polyaniline with improved electrochemical behaviour for solid-state chemical sensor applications [J].
Boeva, Zhanna A. ;
Milakin, Konstantin A. ;
Pesonen, Markus ;
Ozerin, Aleksander N. ;
Sergeyev, Vladimir G. ;
Lindfors, Tom .
RSC ADVANCES, 2014, 4 (86) :46340-46350
[10]   The birth of zinc anode-based electrochromic devices [J].
Chen, Jingwei ;
Xu, Bing ;
Zhang, Yingxin ;
Zhang, Wu ;
Wang, Huanlei ;
Elezzabi, Abdulhakem Y. ;
Liu, Linhua ;
Yu, William W. ;
Li, Haizeng .
APPLIED PHYSICS REVIEWS, 2024, 11 (01)