Activity, stability, and kinetic study of CuO/TiO2 Janus photocatalyst for Rhodamine B degradation

The CuO/TiO2 photocatalyst was synthesized using hydrothermal and sonochemical methods and subsequently applied to degrade rhodamine B in wastewater. The best synthesis conditions were established, determining Cu(NO3)(2) solution concentration of 2.5 wt.% and calcination temperature of 500 degrees C. The CuO/TiO2 photocatalyst underwent characterization through various techniques, including ICP, photoluminescence, X-ray diffraction, ASAP, scanning electron microscope (SEM), EDAX, transmission electron microscopy (TEM), and diffuse reflectance spectroscopy. TEM and SEM analyses revealed the presence of TiO2 nanowires and CuO nanoparticles. The Box-Behnken design, encompassing 27 experimental runs, assessed the impact of process variables such as initial dye concentration, pH, UV lamp power, and catalyst dose on the degradation process. The model's R-2 value of 0.9893 indicated a high precision in fitting the predicted data to their actual values. Analysis of variance results highlighted UV irradiation power as the most significant variable within the design space. In addition, the CuO/TiO2 photocatalyst demonstrated efficacy under visible light irradiation. Light-expanded clay aggregate beads were chosen as the substrate for photocatalyst immobilization, which enhanced the reaction rate. The stability of CuO/TiO2 was evidenced by about 2% reduction in efficiency after four degradation cycles.