Synthesis of hydroxy acids via the light-driven carboxylation of epoxides with CO2

被引：1
作者：
Maeda, Chihiro [1 ]
Kumemoto, Ren [1 ]
Tanaka, Rio [1 ]
Ema, Tadashi [1 ]
机构：
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Appl Chem, 3-1-1Tsushima Naka,Kita Ku, Okayama 7008530, Japan
来源：
CHEMISTRY LETTERS | 2024年 / 53卷 / 05期
关键词：
CO2; fixation; epoxides; light-driven carboxylation; CARBON-DIOXIDE; CATALYZED CARBOXYLATION; CYCLIC CARBONATES; FIXATION; HALIDES;
D O I：
10.1093/chemle/upae086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light-driven ring-opening carboxylation of epoxides with CO2 provided beta-hydroxy acids via sequential single electron transfer (SET), followed by reaction with CO2. This reaction condition was applicable to aryl epoxides and oxetanes with (hetero)polycyclic aromatics to give the corresponding beta- and gamma-hydroxy acids, respectively, with high chemoselectivity.
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页数：4
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