Morphological, thermal and mechanical properties of wheat-straw reinforced copper nanocomposite

被引:0
作者
Haque, Md. Eyazul [1 ]
Chowdhury, Md. Najmul Kabir [2 ]
Khan, Md. Wahab [1 ,3 ]
机构
[1] Bangladesh Univ Engn & Technol, Fac Sci, Dept Chem, Dhaka 1000, Bangladesh
[2] Dhaka Coll, Dept Chem, Dhaka, Bangladesh
[3] Int Univ Business Agr & Technol, Coll Arts & Sci, Dept Chem, Dhaka, Bangladesh
关键词
mechanical properties; morphology; nanocomposite; thermogravimetric analysis; waste; FIBER; NANOPARTICLE; COMPOSITES; BEHAVIOR; POLYMER;
D O I
10.1002/pc.28777
中图分类号
TB33 [复合材料];
学科分类号
摘要
The work summarizes an innovative nanocomposite including synthesized copper nanoparticle (CuNP) impregnated wheat straw (WS) (the agronomic waste from an wheat plant) reinforced unsaturated polyester resin has been established. The addition of nanoparticles (NPs) increased the antifungal properties (similar to 11%), durability (similar to 9%), and strength (similar to 39%) of the composites. Therefore, these nanoparticles have been synthesized from a copper chloride dihydrate precursor and they have been impregnated into wheat straw via cationization. This copper-impregnated wheat straw (CuIWS) was formulated and employed to create a strong and long-lasting nanocomposite with unsaturated polyester resin. Their morphological, mechanical, chemical, biodegradability (BD), and thermal properties were estimated and relationships were explicated systematically. Particularly, the tensile strength of polyester resin, crude and treated WS (cationized and copper-impregnated) composites were 11.70, 14.20, 20.92, and 22.34 N/mm2 respectively. Therefore the reinforcement capability for crude, cationized and copper-impregnated WS composites increased by similar to 22%, 75%, and 92% respectively. The residual ash was just about 16.23%, 12.04% and 6.56% for copper impregnated wheat straw composite (CuIWSC), Cationized wheat straw composite (CWSC) and untreated wheat straw composite (UTWSC) respectively point to the existence of similar to 4.1% Cu incorporated into the wheat straw which holds up the energy dispersive x-ray (EDX) spectra of similar to 4.2% copper content. Thermogravimetric analysis (TGA) indicates that the nanocomposites are stable up to 325 degrees C. These nanocomposites also show superlative crystallinity compared to other ones. Water uptake capacity followed typical Fickian diffusion law. The developed nanocomposites might be suitable for automobile and aircraft parts, furniture, and other indoor to outdoor applications. Highlights TS of the composites increased by increasing the WS filling up to 15%. The crystallinity increased after the addition of nanoparticles. The typical water uptake properties followed the Fickian diffusion rule. Incorporation of nanoparticles increased 11% antifungal properties. The developed nanocomposites are used for inside and outside applications.
引用
收藏
页码:14384 / 14397
页数:14
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