Evaluating the native oxide of titanium as an electrocatalyst for oxalic acid reduction

被引：1

作者：

Sale, Halilu ^{[1
,2
]}

Ertekin, Zeliha ^{[1
,3
]}

Lalaguna, Paula L. ^{[1
]}

Kadodwala, Malcolm ^{[1
]}

Symes, Mark D. ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Scotland

[2] Energy Commiss Nigeria, Plot 701c, Garki Abuja, Nigeria

[3] Hacettepe Univ, Fac Sci, Dept Chem, TR-06800 Beytepe, Ankara, Turkiye

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

FILM; SPECTROSCOPY;

D O I：

10.1039/d4cc01176g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we show that unmodified titanium electrodes bearing the naturally-forming native TixOy coating display superior activity for the electroreduction of oxalic acid to glyoxylic acid and glycolic acid compared to Ti-based electrodes that have been deliberately modified for this purpose, in terms of both oxalic acid conversion and overall yields of reduced products. Titanium electrodes bearing the naturally-forming native oxide coating are competent for the electroreduction of oxalic acid to glyoxylate and glycolate.

引用

页码：6003 / 6006

页数：4

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