A low Pt-loaded electrode electrochemically synthesized from bulk metal for electrocatalytic applications

被引：4

作者：

Lu, Xiaofeng ^{[1
]}

Wu, Shizhao ^{[1
]}

Zheng, Shitao ^{[1
]}

Sun, Xinying ^{[1
]}

Wang, Enjie ^{[1
]}

Chu, Youqun ^{[1
,2
,3
]}

Gao, Jing ^{[1
,2
,3
]}

Li, Guohua ^{[1
,2
,3
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China

[2] State Key Lab Breeding Base Green Chem Synth Techn, Hangzhou, Peoples R China

[3] Key Lab Green Chem Synth Technol Zhejiang Prov, Hangzhou, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2024年 / 12卷 / 27期

基金：

中国国家自然科学基金;

关键词：

HYDROGEN EVOLUTION; OXYGEN REDUCTION; METHANOL; PERFORMANCE;

D O I：

10.1039/d4ta02022g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The design of economical, efficient, and durable low-Pt catalysts is one of the directions in developing energy storage and conversion technologies. Herein, a Pt/WC1-x/WO3 self-supported electrode with a low Pt-loading (17.4 mu g cm-2) was synthesized from bulk metals by an anodization coupled electrodeposition method followed by a carburization reduction process. The electrode exhibits an overpotential of 89.6 mV at 200 mA cm-2 for the hydrogen evolution reaction (HER) with excellent stability. Its highest mass activity for the methanol oxidation reaction (MOR) is 1.18 A mg-1 Pt, which is 2.46 times higher than that of a 20% Pt/C catalyst. This self-supporting electrode also shows excellent stability and resistance to CO poisoning. These can be attributed to the synergistic effects among Pt, WC1-x and WO3, and the heterogeneous interface between them, which accelerates the process of hydrogen absorption and desorption on their surface. These results suggest that the anodization coupled electrodeposition method is an efficient approach to design low Pt-loaded self-supporting electrodes with high activity and stability. A Pt/WC1-x/WO3 self-supported electrode is fabricated from bulk metals by a electrochemical method. The interfacial effect of Pt and WC1-x/WO3 regulates the adsorption/desorption and transfer of Hads, thus optimizing the electrocatalytic performance.

引用

页码：16583 / 16591

页数：9

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