Corrosion behavior of (Cr2/3Ti1/3)3AlC2 and Ti3AlC2 in static liquid lead-bismuth eutectic

被引：0
|
作者：
Zhang, Xinyue [1 ,2 ]
Ren, Yan [3 ]
Xu, Jingjun [1 ]
Gai, Xin [3 ]
Li, Yang [1 ,2 ]
Ma, Ke [1 ]
Zhao, Ke [3 ]
Li, Xingchao [4 ]
Li, Tongqi [4 ]
机构：
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
[2] Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei, Peoples R China
[3] Nucl Power Inst China, Natl Key Lab Nucl Reactor Technol, Chengdu, Peoples R China
[4] Aerosp Res Inst Mat & Proc Technol, Sci & Technol Adv Funct Composites Lab, Beijing, Peoples R China
来源：
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY | 2024年 / 21卷 / 06期
关键词：
(Cr2/3Ti1/3)(3)AlC2; LBE corrosion; oxygen-depleted corrosion; Ti3AlC2; M(N+1)AX(N) PHASES; TI2ALC; IRRADIATION; OXYGEN; OXIDATION; CARBIDES; DEFECTS; TI3SIC2; LBE;
D O I：
10.1111/ijac.14836
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Corrosion behavior of (Cr2/3Ti1/3)(3)AlC2 and Ti3AlC2 in static oxygen-saturated liquid lead-bismuth eutectic (LBE) at 550 degrees C and (Cr2/3Ti1/3)(3)AlC2 in static oxygen-depleted LBE at 500 degrees C were investigated. In oxygen-saturated corrosion, the loose and porous corrosion layer consisting of (PbTiO3 + TiO2) was generated on the surface of Ti3AlC2. In contrast, (Cr2/3Ti1/3)(3)AlC2 formed the protective Cr2O3 layer with better corrosion resistance. Moreover, dissolution corrosion of (Cr2/3Ti1/3)(3)AlC2 in oxygen-depleted corrosion was intensified without a protective oxide film. And impurity phase TiC on the surface also caused the decomposition of matrix, thus impairing corrosion resistance.
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收藏
页码：4257 / 4269
页数：13
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