Measurement and correlation of solubility data for sodium picosulphate in selected pure solvents and mixed-solvent systems from 298.15 K to 328.15 K

被引:4
作者
Raijada, Ankita [1 ]
Bhola, Ravibhai [2 ]
Buch, Munishkumar [2 ]
Ghumara, Rizwan [3 ]
Patel, Chirag [4 ]
Jain, Vicky [1 ]
机构
[1] Marwadi Univ, Dept Chem, Rajkot 360003, Gujarat, India
[2] Ganpat Univ, Dept Chem, Kherva 384012, Gujarat, India
[3] Tolani Coll Arts & Sci, Dept Chem, Adipur 370205, Gujarat, India
[4] Krantiguru Shyamji Krishna Verma Kachchh Univ, Dept Chem, Bhuj 370001, Gujarat, India
关键词
Solubility; Van 't Hoff model; Apelblat model; Sodium Picosulphate; PICOSULFATE/MAGNESIUM CITRATE; POLYETHYLENE-GLYCOL; COLONOSCOPY; ACID; WATER; THERMODYNAMICS; METAANALYSIS;
D O I
10.1016/j.molliq.2024.125044
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An investigation was carried out to determine the solubility of the stimulant laxative drug Sodium Picosulphate (SP). A wide range of pure solvents were studied, including methanol, ethanol, 1-propanol, 1-butanol, dimethyl formamide, dimethyl sulfoxide, acetonitrile, 1,4-dioxane, acetic acid, and water. More to the point, the solubility of the compound was determined using mixed solvent systems; methanol + acetonitrile and water + acetonitrile. Experimental mole fraction solubility of SP was determined by the gravimetric method over a range of temperatures (298.15 K to 328.15 K) under atmospheric pressure (p = 0.1MPa). According to experimental results, a temperature-dependent relationship exists between solubility and temperature. Further, we correlated the experimental mole fraction solubility data with theoretical models including Apelblat, Yaws, Van't Hoff, Modified Jouyban-Acree, CNIBS/R -K models. It appears that the results are well in agreement with the experimental results due to the small values of relative average deviation (RAD) and root mean square deviation (RMSD).The solubility data might be useful in the various areas such as modification, production, crystallization, and separation of SP.
引用
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页数:9
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