Carbon nanodots from orange peel waste as fluorescent probes for detecting nitrobenzene

被引:13
作者
Michenzi, Cinzia [1 ]
Proietti, Anacleto [1 ]
Rossi, Marco [1 ]
Espro, Claudia [2 ]
Bressi, Viviana [2 ]
Vetica, Fabrizio [3 ]
Simonis, Beatrice [4 ]
Chiarotto, Isabella [1 ]
机构
[1] Sapienza Univ Rome, Dept Basic & Appl Sci Engn SBAI, Via Castro Laurenziano 7, I-00161 Rome, Italy
[2] Univ Messina, Dept Engn, I-98166 Messina, Italy
[3] Sapienza Univ Rome, Dept Chem, Piazzale Aldo Moro 5, I-00185 Rome, Italy
[4] Sapienza Univ Rome, Inst Biol Syst Italian Natl Res Council ISB CNR, Secondary Off Rome React Mech, Dept Chem, Piazzale Aldo Moro 5, I-00185 Rome, Italy
来源
RSC SUSTAINABILITY | 2024年 / 2卷 / 04期
关键词
QUANTUM DOTS; GREEN; SENSOR;
D O I
10.1039/d3su00469d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitro aromatic compounds have been recognized as hazardous and carcinogenic substances for more than three decades. However, even today, they persist as pervasive pollutants in water, soil, and air. Consequently, the development of innovative, user-friendly, and dependable platforms for their rapid and efficient detection remains crucial from both environmental and health perspectives. In this study, we explore the conversion of biomass waste into valuable nanomaterials, specifically carbon dots. These bio-derived carbon dots exhibit promising photoluminescence properties and are effectively utilized as fluorescent chemical probes for the detection of nitrobenzene, all without the need for additional late-stage functionalization or surface modification. The insights gained from this research can contribute to the development of an environmentally friendly and sustainable approach to nitrobenzene detection. Notably, our research highlights that unmodified carbon dots in an aqueous solution can detect low concentrations of nitrobenzene. An integrated approach combining thermal and electrochemical technologies for the valorization of agro-industrial waste. The resulting carbon dots (CDs) show fascinating optical properties, enabling their application as fluorescent chemical probes.
引用
收藏
页码:933 / 942
页数:11
相关论文
共 50 条
[1]   Fluorescent carbon nanodots as efficient nitro aromatic sensor-analysis based on computational perspectives [J].
Ansi, V. A. ;
Vijisha, K. R. ;
Muraleedharan, K. ;
Renuka, N. K. .
SENSORS AND ACTUATORS A-PHYSICAL, 2020, 302
[2]   Toxicity and Microbial Degradation of Nitrobenzene, Monochloronitrobenzenes, Polynitrobenzenes, and Pentachloronitrobenzene [J].
Arora, Pankaj Kumar ;
Bae, Hanhong .
JOURNAL OF CHEMISTRY, 2014, 2014 :1-12
[3]   Sustainable synthesis of carbon quantum dots from banana peel waste using hydrothermal process for in vivo bioimaging [J].
Atchudan, Raji ;
Edison, Thomas Nesakumar Jebakumar Immanuel ;
Shanmugam, Mani ;
Perumal, Suguna ;
Somanathan, Thirunavukkarasu ;
Lee, Yong Rok .
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2021, 126
[4]   Facile and green synthesis of fluorescent carbon dots from onion waste and their potential applications as sensor and multicolour imaging agents [J].
Bandi, Rajkumar ;
Gangapuram, Bhagavanth Reddy ;
Dadigala, Ramakrishna ;
Eslavath, Ravikumar ;
Singh, Surya S. ;
Guttena, Veerabhadram .
RSC ADVANCES, 2016, 6 (34) :28633-28639
[5]   Current status and prospects on chemical structure driven photoluminescence behaviour of carbon dots [J].
Barman, Monoj Kumar ;
Patra, Amitava .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2018, 37 :1-22
[6]  
Beny-Bassez C., 1984, Scanning Electron Microsc, V1, P119
[7]   Voltammetric Sensor Based on Waste-Derived Carbon Nanodots for Enhanced Detection of Nitrobenzene [J].
Bressi, Viviana ;
Chiarotto, Isabella ;
Ferlazzo, Angelo ;
Celesti, Consuelo ;
Michenzi, Cinzia ;
Len, Thomas ;
Iannazzo, Daniela ;
Neri, Giovanni ;
Espro, Claudia .
CHEMELECTROCHEM, 2023, 10 (13)
[8]   Bladder cancer incidence among workers exposed to o-toluidine, aniline and nitrobenzene at a rubber chemical manufacturing plant [J].
Carreon, Tania ;
Hein, Misty J. ;
Hanley, Kevin W. ;
Viet, Susan M. ;
Ruder, Avima M. .
OCCUPATIONAL AND ENVIRONMENTAL MEDICINE, 2014, 71 (03) :175-182
[9]   Design and applications of carbon dots-based ratiometric fluorescent probes: A review [J].
Chen, Bin-Bin ;
Liu, Meng-Li ;
Gao, Ya-Ting ;
Chang, Shuai ;
Qian, Ruo-Can ;
Li, Da-Wei .
NANO RESEARCH, 2023, 16 (01) :1064-1083
[10]   So you think your process is green, how do you know? Using principles of sustainability to determine what is green - a corporate perspective [J].
Curzons, AD ;
Constable, DJC ;
Mortimer, DN ;
Cunningham, VL .
GREEN CHEMISTRY, 2001, 3 (01) :1-6