Ultralow-Power Single-Sensor-Based E-Nose System Powered by Duty Cycling and Deep Learning for Real-Time Gas Identification

被引:11
作者
Kim, Taejung [1 ]
Kim, Yonggi [2 ]
Cho, Wootaek [1 ]
Kwak, Jong-Hyun [1 ]
Cho, Jeonghoon [2 ]
Pyeon, Youjang [2 ]
Kim, Jae Joon [2 ]
Shin, Heungjoo [1 ]
机构
[1] Ulsan Natl Inst Sci & Technol UNIST, Dept Mech Engn, Ulsan 44919, South Korea
[2] Ulsan Natl Inst Sci & Technol UNIST, Dept Elect Engn, Ulsan 44919, South Korea
基金
新加坡国家研究基金会;
关键词
metal oxide semiconductor; ultralow power; electronic nose; nanoheater; duty cycling; deep learning; real-time identification; MOLECULE-COLLISION PROCESSES; ELECTRON-AFFINITIES; TEMPERATURE MODULATION; NEGATIVE-IONS; SO2; CONDUCTIVITY; DISCRIMINATION; ALGORITHMS; O-2; H-2;
D O I
10.1021/acssensors.4c00471
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This study presents a novel, ultralow-power single-sensor-based electronic nose (e-nose) system for real-time gas identification, distinguishing itself from conventional sensor-array-based e-nose systems, whose power consumption and cost increase with the number of sensors. Our system employs a single metal oxide semiconductor (MOS) sensor built on a suspended 1D nanoheater, driven by duty cycling-characterized by repeated pulsed power inputs. The sensor's ultrafast thermal response, enabled by its small size, effectively decouples the effects of temperature and surface charge exchange on the MOS nanomaterial's conductivity. This provides distinct sensing signals that alternate between responses coupled with and decoupled from the thermally enhanced conductivity, all within a single time domain during duty cycling. The magnitude and ratio of these dual responses vary depending on the gas type and concentration, facilitating the early stage gas identification of five gas types within 30 s via a convolutional neural network (classification accuracy = 93.9%, concentration regression error = 19.8%). Additionally, the duty-cycling mode significantly reduces power consumption by up to 90%, lowering it to 160 mu W to heat the sensor to 250 degree celsius. Manufactured using only wafer-level batch microfabrication processes, this innovative e-nose system promises the facile implementation of battery-driven, long-term, and cost-effective IoT monitoring systems.
引用
收藏
页码:3557 / 3572
页数:16
相关论文
共 65 条
[11]   Generic Approach to Boost the Sensitivity of Metal Oxide Sensors by Decoupling the Surface Charge Exchange and Resistance Reading Process [J].
Dai, Tiantian ;
Meng, Gang ;
Deng, Zanhong ;
Chen, Ying ;
Liu, Hongyu ;
Li, Liang ;
Wang, Shimao ;
Chang, Junqing ;
Xu, Pengcheng ;
Li, Xinxin ;
Fang, Xiaodong .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (33) :37295-37304
[12]   Semiconductor metal oxide gas sensors: A review [J].
Dey, Ananya .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2018, 229 :206-217
[13]   A review on efficient self-heating in nanowire sensors: Prospects for very-low power devices [J].
Fabrega, C. ;
Casals, O. ;
Hernandez-Ramirez, F. ;
Prades, J. D. .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 256 :797-811
[14]   Mixed-scale poly(methyl methacrylate) channel network-based single-particle manipulation via diffusiophoresis [J].
Hong, Jisoo ;
Kim, Beomsang ;
Shin, Heungjoo .
NANOSCALE, 2018, 10 (30) :14421-14431
[15]   A theoretical investigation of the power-law response of metal oxide semiconductor gas sensors I: Schottky barrier control [J].
Hua, Zhongqiu ;
Li, Yan ;
Zeng, Yan ;
Wu, Yi .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 :1911-1919
[16]   ELECTRON AFFINITIES FROM ENDOTHERMIC NEGATIVE-ION CHARGE-TRANSFER REACTIONS .3. NO, NO2, SO2, CS2, CL2, BR2, I2, AND C2H [J].
HUGHES, BM ;
LIFSHITZ, C ;
TIERNAN, TO .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (06) :3162-3181
[17]   A low-power embedded poly-Si micro-heater for gas sensor platform based on a FET transducer and its application for NO2 sensing [J].
Jung, Gyuweon ;
Hong, Yoonki ;
Hong, Seongbin ;
Jang, Dongkyu ;
Jeong, Yujeong ;
Shin, Wonjun ;
Park, Jinwoo ;
Kim, Donghee ;
Jeong, Chan Bae ;
Kim, Dong Uk ;
Chang, Ki Soo ;
Lee, Jong-Ho .
SENSORS AND ACTUATORS B-CHEMICAL, 2021, 334
[18]   A human pilot trial of ingestible electronic capsules capable of sensing different gases in the gut [J].
Kalantar-Zadeh, Kourosh ;
Berean, Kyle J. ;
Ha, Nam ;
Chrimes, Adam F. ;
Xu, Kai ;
Grando, Danilla ;
Ou, Jian Zhen ;
Pillai, Naresh ;
Campbell, Jos L. ;
Brkljaca, Robert ;
Taylor, Kirstin M. ;
Burgell, Rebecca E. ;
Yao, Chu K. ;
Ward, Stephanie A. ;
McSweeney, Chris S. ;
Muir, Jane G. ;
Gibson, Peter R. .
NATURE ELECTRONICS, 2018, 1 (01) :79-87
[19]   High Accuracy Real-Time Multi-Gas Identification by a Batch-Uniform Gas Sensor Array and Deep Learning Algorithm [J].
Kang, Mingu ;
Cho, Incheol ;
Park, Jaeho ;
Jeong, Jaeseok ;
Lee, Kichul ;
Lee, Byeongju ;
Henriquez, Dionisio Del Orbe ;
Yoon, Kukjin ;
Park, Inkyu .
ACS SENSORS, 2022, 7 (02) :430-440
[20]   Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview [J].
Kim, Hyo-Joong ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 192 :607-627