Carbonic anhydrase-mimicking metal-organic frameworks built from amino acid and cadmium ions

被引:1
|
作者
Ogungbade, Taofeek [1 ]
Uland, Charles [1 ]
Li, Longji [1 ]
Wang, Luhan [1 ]
Pansuria, Kareena [1 ]
Relva, Carolina [1 ]
Barn, Gregory [1 ]
Kaur, Simrat Jeet [1 ]
Norris, Paulin [2 ]
Yan, Bangbo [1 ,2 ]
机构
[1] Western Kentucky Univ, Dept Chem, 1906 Coll Hts Blvd, Bowling Green, KY 42101 USA
[2] Western Kentucky Univ, Adv Mat Inst, 2413 Nashville Rd, Bowling Green, KY 42101 USA
关键词
CAPTURE; ZINC; EVOLUTION; SITE; CO2;
D O I
10.1039/d4dt01456a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Built from l-histidine amino acid ligand and cadmium ions, two new 3D chiral metal-organic frameworks, [alpha-Cd(HIS)] (1) and [beta-Cd(HIS)] (2), which contain metal-histidine bonds mimicking the structure features of carbonic anhydrase, demonstrate interesting properties of catalyzing the hydrolysis of p-nitrophenylacetate (p-NPA) to para-nitrophenol (p-NP). Two new 3D metal-organic framework materials, assembled from l-histidine amino acid and cadmium ions, show catalytic properties similar to carbonic anhydrase.
引用
收藏
页码:11228 / 11231
页数:4
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