AGA8 supported Cu(I) nanoclusters as in situ generated catalysts for room temperature C-S coupling reactions in water

被引：1

作者：

Jin, Hao ^{[1
,2
]}

Fan, Yun ^{[1
,2
]}

Liu, Penghao ^{[1
,2
]}

Meng, Qi ^{[1
,2
]}

Teng, Qiaoqiao ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Gehu Rd 21, Changzhou 213164, Peoples R China

[2] Changzhou Univ, Jiangsu Prov Engn Res Ctr Biodegradable Mat, Changzhou, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2024年 / 38卷 / 08期

基金：

中国国家自然科学基金;

关键词：

C-S coupling; in situ reduction; nanocluster catalyst; sugar-based surfactants; sustainability; ORGANIC DISULFIDES; EFFICIENT; GLIOTOXIN; DRUG;

D O I：

10.1002/aoc.7538

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A sustainable and green catalytic strategy for C-S coupling reactions is developed by combining micelle and transition metal. The synergistic AGA8@Cu(I) catalyst forms by spontaneous anchoring of the in situ generated Cu(I) nanoclusters onto the AGA8 micelles and has been fully characterized by FT-IR, XPS, SEM, TEM, EDS, and ICP-OES. The catalyst is recyclable and highly effective in mediating the conversion of halides to disulfides in water at room temperature with a broad substrate scope. A recyclable AGA8@Cu(I) nanocluster generated by in situ reduction was demonstrated to promote the synthesis of disulfides from chlorides and Na2S2O3 in water at room temperature. image

引用

页数：10

共 7 条

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