Silicon/Silicon Carbide/Graphite Composite Anode Material for Rechargeable Lithium-Ion Batteries by High-Temperature Vacuum Adsorption Method

被引:0
作者
Wang, Liyong [1 ]
Wang, Mei [1 ]
Wang, Huiqi [1 ]
Yang, Jinhua [2 ]
Ji, Shengsheng [1 ]
Liu, Lei [1 ]
Hu, Shengliang [1 ]
Guo, Quangui [3 ]
机构
[1] North Univ China, Sch Energy & Power Engn, Taiyuan 030001, Peoples R China
[2] AECC Beijing Inst Aeronaut Mat, Natl Key Lab Adv Composites, Beijing 10095, Peoples R China
[3] Chinese Acad Sci, CAS Key Lab Carbon Mat, Inst Coal Chem, Taiyuan 0310001, Shanxi, Peoples R China
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2024年 / 46卷 / 03期
基金
中国国家自然科学基金;
关键词
Silicon; Expanded graphite; Lithium-ion battery; Anode; High-temperature vacuum adsorption; SILICON-CARBIDE; HIGH-ENERGY; CARBON; RAMAN;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recently, the electrode materials for next-generation lithium-ion batteries (LIBs) draw widespread attention on storing reversibly the electrical energy. For this issue, the expanded graphite and silicon particles are chosen to generate silicon/silicon carbide/graphite composite anode material using a high-temperature vacuum adsorption method. The prepared composites are measured by Xray diffraction, transmission electron microscopy, and Raman spectra, et al. The composites are cycled at a current density of 50 mA g(-1), in order to observe their potential specific capacity. An initial charge capacity is 566.5 mAh g(-1), and its initial Coulombic efficiency is 97.4 %. The reversible specific capacity keeps at 502 mAh g(-1) after 80 cycles, displaying a capacity retention of 88.7%.
引用
收藏
页码:241 / 252
页数:12
相关论文
共 59 条
[1]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[2]   MECHANISMS FOR LITHIUM INSERTION IN CARBONACEOUS MATERIALS [J].
DAHN, JR ;
ZHENG, T ;
LIU, YH ;
XUE, JS .
SCIENCE, 1995, 270 (5236) :590-593
[3]   Spray-drying construction of nickel/cobalt/molybdenum based nano carbides embedded in porous carbon microspheres for lithium-ion batteries as anodes [J].
Denis, Dienguila Kionga ;
Zaman, Fakhr Uz ;
Hou, Linrui ;
Chen, Guozhu ;
Yuan, Changzhou .
ELECTROCHIMICA ACTA, 2022, 424
[4]   Post-lithium-ion battery cell production and its compatibility with lithium-ion cell production infrastructure [J].
Duffner, Fabian ;
Kronemeyer, Niklas ;
Tuebke, Jens ;
Leker, Jens ;
Winter, Martin ;
Schmuch, Richard .
NATURE ENERGY, 2021, 6 (02) :123-134
[5]   The Regulating Role of Carbon Nanotubes and Graphene in Lithium-Ion and Lithium-Sulfur Batteries [J].
Fang, Ruopian ;
Chen, Ke ;
Yin, Lichang ;
Sun, Zhenhua ;
Li, Feng ;
Cheng, Hui-Ming .
ADVANCED MATERIALS, 2019, 31 (09)
[6]   First principles study of layered silicon carbide as anode in lithium ion battery [J].
Fatima, Afrinish ;
Majid, Abdul ;
Haider, Sajjad ;
Akhtar, Muhammad Saeed ;
Alkhedher, Mohammad .
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2022, 122 (11)
[7]   Binder-free nanostructured germanium anode for high resilience lithium-ion battery [J].
Fugattini, S. ;
Gulzar, U. ;
Andreoli, A. ;
Carbone, L. ;
Boschetti, M. ;
Bernardoni, P. ;
Gjestila, M. ;
Mangherini, G. ;
Camattari, R. ;
Li, T. ;
Monaco, S. ;
Ricci, M. ;
Liang, S. ;
Giubertoni, D. ;
Pepponi, G. ;
Bellutti, P. ;
Ferroni, M. ;
Ortolani, L. ;
Morandi, V ;
Vincenzi, D. ;
Zaccaria, R. Proietti .
ELECTROCHIMICA ACTA, 2022, 411
[8]   Multifunctional Utilization of Pitch-Coated Carbon Fibers in Lithium-Based Rechargeable Batteries [J].
Ghosh, Shuvajit ;
Bhattacharjee, Udita ;
Patchaiyappan, Sivaraman ;
Nanda, Jagjit ;
Dudney, Nancy J. ;
Martha, Surendra K. .
ADVANCED ENERGY MATERIALS, 2021, 11 (17)
[9]   The study of the iridium - silicon carbide reaction by Raman and IR spectroscopy [J].
Golosov, Mikhail ;
Lozanov, Victor ;
Baklanova, Natalya .
MATERIALS TODAY-PROCEEDINGS, 2020, 25 :352-355
[10]   Lattice-Coupled Si/MXene Confined by Hard Carbon for Fast Sodium-Ion Conduction [J].
Gou, Li ;
Jing, Weifeng ;
Li, Ying ;
Wang, Mei ;
Hu, Shengliang ;
Wang, Huiqi ;
He, Yan-Bing .
ACS APPLIED ENERGY MATERIALS, 2021, 4 (07) :7268-7277