Arduino Controlled Catalytic Pyrolysis of Plastic/Municipal Waste to Higher Hydrocarbons

被引:0
作者
Nadeem, Saad [1 ]
Muhbat, Sajid [1 ]
Zakaria, Kamran [3 ]
Mustafa, Ghulam [2 ]
机构
[1] NED Univ Engn & Technol, Chem Engn Dept, Karachi 75300, Pakistan
[2] NED Univ Engn & Technol, Dept Phys, Karachi 75270, Pakistan
[3] NED Univ Engn & Technol, Dept Math, Karachi 75270, Pakistan
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2024年 / 46卷 / 02期
关键词
Fuel; Catalyst; Waste to energy; Pyrolysis; Arduino; PLASTIC WASTE; OIL; FUEL;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Worldwide, the broad usage of plastic has resulted in the massive production of plastic pollution. In this work, it was demonstrated that municipal plastic waste could be converted into valuable liquid products. This study shows the catalytic and non -catalytic pyrolysis of low -density polyethylene (LDPE), polypropylene (PP), and high -density polyethylene (HDPE). Pyrolysis was carried out in the absence of Oxygen, and three types of fractions: gas, liquid, and solid residues were obtained. The proportions of liquid or gas residue depend on the operating conditions such as temperature and the type of catalyst. The product obtained was then characterized through ASTM D97, ASTM D-86, ASTM D-4294, Cloud Point, Conradson Carbon Residue, FTIR Analysis, ASTM D-611, Density and Specific Gravity. The use of catalysts showed more quantity of lower boiling points products due to further cracking of carbon chains and pour points decrease was also observed generally with the use of catalyst specially by using bentonite. A decrease in Pour Point indicated a decrease in paraffin content, therefore, reducing wax content, and so it indicated better flow properties at lower temperatures. Pour point and viscosity observed were interconnected with each other, sample having high pour points had high viscosity, hence showing the flowing ability of the liquid. Also, the Sulphur contents of all the samples falling under Euro II and Euro II category. C -S-tretching, C=S-tretching and C -B ending bonds were noted using the FTIR analysis. One of the important purposes of this study was to convert the waxes obtained from thermal pyrolysis of HDPE and LDPE to higher chain hydrocarbons, which was achieved by using bentonite as the catalyst and also flowing properties of the liquid improved by using the catalyst. HDPE with bentonite gave the highest percent of liquid fuel (75.15%) obtained which in turn shows the best result obtained through all our experiments.
引用
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页码:219 / 232
页数:14
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