An organophosphate 3d-4f heterometallic polyoxoniobate nanowire

被引:3
作者
Fan, Jin-Ai [1 ]
Yu, Hao [1 ]
Lin, Yu-Diao [1 ,2 ]
Qi, Ming-Qiang [3 ]
Kong, Xiang-Jian [3 ]
Sun, Cai [1 ]
Zheng, Shou-Tian [1 ]
机构
[1] Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[2] Fujian Polytech Normal Univ, Fujian Prov Key Lab Coastal Basin Environm, Fuqing 350300, Fujian, Peoples R China
[3] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
基金
中国国家自然科学基金;
关键词
POLYOXOMETALATE; COMPLEXES;
D O I
10.1039/d4nr01619j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four different structural compositions of organophosphate, 3d transition metal, 4f lanthanide and polyoxoniobate (PONb) are unified in a system for the first time to form a new type of organophosphate 3d-4f heterometallic inorganic-organic hybrid PONb nanowire. Interesting magnetic anisotropy and slow magnetic relaxation are found in the PONb nanowire. Integrate four structural compositions of organophosphate, 3d transition metal, 4f lanthanide and polyoxoniobate at the molecular level, to form a nanowire structure.
引用
收藏
页码:12420 / 12423
页数:4
相关论文
共 32 条
  • [1] Magnetostructural correlations in the tetranuclear series of {Fe3LnO2} butterfly core clusters: Magnetic and Moumlssbauer spectroscopic study
    Bartolome, J.
    Filoti, G.
    Kuncser, V.
    Schinteie, G.
    Mereacre, V.
    Anson, C. E.
    Powell, A. K.
    Prodius, D.
    Turta, C.
    [J]. PHYSICAL REVIEW B, 2009, 80 (01)
  • [2] Rare Earth Polyoxometalates
    Boskovic, Colette
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (09) : 2205 - 2214
  • [3] Anion-Dependent Assembly of Heterometallic 3d-4f Clusters Based on a Lacunary Polyoxometalate
    Cai, Jing
    Zheng, Xiu-Ying
    Xie, Jing
    Yan, Zhi-Hao
    Kong, Xiang-Jian
    Ren, Yan-Ping
    Long, La-Sheng
    Zheng, Lan-Sun
    [J]. INORGANIC CHEMISTRY, 2017, 56 (14) : 8439 - 8445
  • [4] Synergistic Effect between Different Coordination Geometries of Lanthanides and Various Coordination Modes of 2-Picolinic Acid Ligands Tuning Three Types of Rare 3d-4f Heterometallic Tungstoantimonates
    Chen, Yanhong
    Sun, Longhui
    Chang, Shenzhen
    Chen, Lijuan
    Zhao, Junwei
    [J]. INORGANIC CHEMISTRY, 2018, 57 (24) : 15079 - 15092
  • [5] Heterometallic 3d-4f polyoxometalates: An emerging field with structural diversity to multiple applications
    Das, Vivek
    Kaushik, Reetam
    Hussain, Firasat
    [J]. COORDINATION CHEMISTRY REVIEWS, 2020, 413
  • [6] Two rare Cr-Ln (Ln = Dy, Tb) heterometallic cluster substituted polyoxometalates featuring hexameric aggregates: hydrothermal syntheses, crystal structures and magnetic studies
    Gu, Ya-Nan
    Yu, Hao
    Lin, Li-Dan
    Wu, Yan-Lan
    Li, Zhong
    Pan, Wen-Yue
    He, Jiang
    Chen, Ling
    Li, Qi
    Li, Xin-Xiong
    [J]. NEW JOURNAL OF CHEMISTRY, 2019, 43 (07) : 3011 - 3016
  • [7] A Series of Banana-Shaped 3d-4f Heterometallic Cluster Substituted Polyoxometalates: Syntheses, Crystal Structures, and Magnetic Properties
    Gu, Ya-Nan
    Chen, Yi
    Wu, Yan-Lan
    Zheng, Shou-Tian
    Li, Xin-Xiong
    [J]. INORGANIC CHEMISTRY, 2018, 57 (05) : 2472 - 2479
  • [8] Core-Shell-Type All-Inorganic Heterometallic Nanoclusters: Record High-Nuclearity Cobalt Polyoxoniobates for Visible-Light-Driven Photocatalytic CO2 Reduction
    Guo, Zheng-Wei
    Lin, Ling-Hui
    Ye, Jian-Ping
    Chen, Yi
    Li, Xin-Xiong
    Lin, Sen
    Huang, Jian-Dong
    Zheng, Shou-Tian
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (26)
  • [9] Self-Assembly and Photocatalytic Properties of Polyoxoniobates: {Nb24O72}, {Nb32O96}, and {K12Nb96O288} Clusters
    Huang, Peng
    Qin, Chao
    Su, Zhong-Min
    Xing, Yan
    Wang, Xin-Long
    Shao, Kui-Zhan
    Lan, Ya-Qian
    Wang, En-Bo
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) : 14004 - 14010
  • [10] Self-Assembly of a Giant Tetrahedral 3d-4 f Single-Molecule Magnet within a Polyoxometalate System
    Ibrahim, Masooma
    Mereacre, Valeriu
    Leblanc, Nicolas
    Wernsdorfer, Wolfgang
    Anson, Christopher E.
    Powell, Annie K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (51) : 15574 - 15578