ATR-FTIR spectroscopy and Machine learning for sustainable wood sourcing and species Identification: Applications to wood forensics

被引:8
作者
Sharma, Akanksha [1 ]
Garg, Suraj [1 ]
Sharma, Vishal [1 ]
机构
[1] Panjab Univ, Inst Forens Sci & Criminol, Chandigarh 160014, India
关键词
Wood Forensics; ATR-FTIR; Supervised Modelling; Tree -based classifiers; PyCaret; X-RAY-DIFFRACTION; INFRARED-SPECTROSCOPY; HARDWOOD; DNA;
D O I
10.1016/j.microc.2024.110467
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Wood forensics, a vital tool in addressing global concerns surrounding illegal logging and the authenticity of wood products, plays a pivotal role in promoting sustainable forestry practices. The integration of Attenuated Total Reflectance Fourier-Transform Infrared (ATR-FTIR) spectroscopy and machine learning presents a potent approach to streamline identification processes and enhance responsible wood sourcing. ATR-FTIR facilitates the detailed characterization of wood components by analyzing spectral data, revealing unique chemical signatures associated with different wood species. This study focuses on Eucalyptus, Dalbergia, and Populus wood species in India, revealing common peaks related to cellulose, flavones, hemicellulose, and lignin constituents. Isolation Forest (iForest) identifies outliers, subsequently removed for supervised modelling, while Principal Component Analysis (PCA) reduces dimensionality effectively. Tree-based supervised machine learning algorithms, including Decision Tree, Extra Tree, Random Forest, and CatBoost classifiers, enhances the accuracy of wood species discrimination by deciphering complex patterns within ATR-FTIR spectra. Further, evaluation through various performance metrics supports the comparative analysis. The outcomes of this study hold significant value for law enforcement agencies in combating illegal logging and timber trade, and potential applications in quality control for timber industries. This research substantiates its real-world applicability, marking a noteworthy advancement in the evolving field of wood forensics.
引用
收藏
页数:11
相关论文
共 45 条
[21]   Approximation of SHAP Values for Randomized Tree Ensembles [J].
Loecher, Markus ;
Lai, Dingyi ;
Qi, Wu .
MACHINE LEARNING AND KNOWLEDGE EXTRACTION, CD-MAKE 2022, 2022, 13480 :19-30
[22]   THE APPLICATION OF DNA METHODS TO TIMBER TRACKING AND ORIGIN VERIFICATION [J].
Lowe, Andrew J. ;
Cross, Hugh B. .
IAWA JOURNAL, 2011, 32 (02) :251-262
[23]   Forensic Hair Differentiation Using Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy [J].
Manheim, Jeremy ;
Doty, Kyle C. ;
McLaughlin, Gregory ;
Lednev, Igor K. .
APPLIED SPECTROSCOPY, 2016, 70 (07) :1109-1117
[24]   Determination of chemical changes in heat-treated wood using ATR-FTIR and FT Raman spectrometry [J].
Ozgenc, Ozlem ;
Durmaz, Sefa ;
Boyaci, Ismail Hakki ;
Eksi-Kocak, Haslet .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2017, 171 :395-400
[25]  
Pathak M. L., 2020, Banko Janakari, V30, P49, DOI 10.3126/banko.v30i1.29182
[26]   Identification and classification of textile fibres using ATR-FT-IR spectroscopy with chemometric methods [J].
Peets, Pilleriin ;
Leito, Ivo ;
Pelt, Jaan ;
Vahur, Signe .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2017, 173 :175-181
[27]   Vibrational spectroscopy and X-ray diffraction methods to establish the differences between hardwood and softwood [J].
Popescu, Carmen-Mihaela ;
Singurel, Ghita ;
Popescu, Maria-Cristina ;
Vasile, Cornelia ;
Argyropoulos, Dimitris S. ;
Willfor, Stefan .
CARBOHYDRATE POLYMERS, 2009, 77 (04) :851-857
[28]   Spectroscopic techniques for the forensic analysis of textile fibers [J].
Prego Meleiro, Pablo ;
Garcia-Ruiz, Carmen .
APPLIED SPECTROSCOPY REVIEWS, 2016, 51 (04) :258-281
[29]  
Prokhorenkova L, 2018, ADV NEUR IN, V31
[30]  
Radkau Joachim., 2012, Wood: A History