Tridentate κ3-P,P,C iridium complexes: influence of ligand saturation on intramolecular C-H bond activation

被引：0
|
作者：
Demchuk, Mitchell J. [1 ]
Zurakowski, Joseph A. [1 ,2 ]
Drover, Marcus W. [1 ]
机构：
[1] Western Univ, Dept Chem, 1151 Richmond St, London, ON N8K 3G6, Canada
[2] Univ Windsor, Dept Chem & Biochem, 401 Sunset Ave, Windsor, ON N9B 3P4, Canada
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 59期
基金：
加拿大自然科学与工程研究理事会;
关键词：
BETA-HYDROGEN ELIMINATION; TRANSITION-METAL-COMPLEXES; PCP PINCER COMPLEXES; REDUCTIVE ELIMINATION; ALKYL COMPLEXES; DESIGN; NICKEL; DEHYDROGENATION; ABSTRACTION; REACTIVITY;
D O I：
10.1039/d4cc01435a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Whereas kappa(3)-P,C,P-based donor ligands are ubiquitous across synthetic chemistry, related unsymmetric systems having kappa(3)-P,P,C-coordination are comparatively rare. In this contribution, we expose a new kappa(3)-P,P,C ligand system, bearing a C3-anionic linker and its coordination chemistry with iridium. The title ligand has been coordinated in saturated and unsaturated forms. The degree of ligand saturation affected an onward (and unusual) oxidative rearrangement reaction.
引用
收藏
页码：7566 / 7569
页数：5
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