Understanding the phase behavior during CO2 flooding by dissipative particle dynamics

被引:5
作者
Shao, Mingyan [1 ]
Aleksander, Palaev [1 ]
Xia, Yuhong [2 ]
Xu, Huiying [2 ]
Tian, Yifan [1 ]
Fetisov, Vadim [3 ]
Shipachev, A. M. [1 ]
Yang, Zhenqing [2 ]
机构
[1] St Petersburg Min Univ, Dept Petr Engn, 2,21st line, St Petersburg 199106, Russia
[2] China Univ Petr, Coll Sci, Basic Res Ctr Energy Interdisciplinary, Beijing 102249, Peoples R China
[3] Empress Catherine II St Petersburg Min Univ, Dept Petr Engn, St Petersburg, Russia
基金
中国国家自然科学基金;
关键词
Dissipative particle dynamics; Supercritical extraction; Miscible phase; Concentration distribution; CO2; flooding; MARTINI FORCE-FIELD; INTERFACIAL-TENSION; OIL-RECOVERY; SURFACE-CHARGE; SIMULATIONS; INJECTION; LIQUID; TEMPERATURE; STORAGE; DPD;
D O I
10.1016/j.molliq.2024.125514
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Understanding the phase behavior of a CO2-oil-water surfactant system is critical for carbon dioxide flooding engineering. Using dissipative particle dynamics, we investigate how the alkanes in crude oil are extracted after the injection of supercritical carbon dioxide into the formation, and what effect this extraction has on the miscible and immiscible displacement of carbon dioxide and crude oil. The images of the extraction are exhibited at the molecular level, and the effects of temperature and pressure on the extraction are investigated. The phase distribution of carbon dioxide, oil, and water under immiscible phase is simulated using actual reservoir fluid data based on a comprehensive understanding of extraction. Oil tends to be spread at the interface of carbon dioxide and water when it is immiscible. The miscible pictures were generated under conditions of reduced CO2- oil-water miscible pressure by adding surfactants to the CO2-oil-water system, and the fluid distribution characteristics under immiscible and miscible phases were examined. dissipative particle dynamics (DPD) simulation demonstrates that when the molar proportion of carbon dioxide is less than 0.4, the solid phase surface can always create a water film of varied thickness, regardless of whether the surface charge of the solid phase is positive or negative. As the molar fraction of carbon dioxide increases, the water film's thickness decreases.
引用
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页数:13
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