Novel S-N/WO3: Optimization of photocatalytic performance of WO3 by simultaneous existence of S and N in WO3 against MB dye

被引:15
作者
Younas, Ayesha [1 ]
Munir, Rana Mustansar [2 ]
Rizvi, Hassan Imam [1 ]
Iqbal, Tahir [1 ]
Afsheen, Sumera [3 ]
Riaz, K. N. [4 ]
Syed, Asad [5 ]
Elgorban, Abdallah M. [6 ]
Wong, Ling Shing [7 ]
机构
[1] Univ Gujrat, Fac Sci, Dept Phys, Hafiz Hayat Campus, Gujrat 50700, Pakistan
[2] Shenzhen Univ, Inst Adv Study, Coll Phys & Optoelect Engn, Shenzhen 518060, Guangdong, Peoples R China
[3] Univ Gujrat, Fac Sci, Dept Zool, Hafiz Hayat Campus, Gujrat 50700, Pakistan
[4] Univ Okara, Dept Phys, Okara, Pakistan
[5] King Saud Univ, Coll Sci, Dept Bot & Microbiol, POB 2455, Riyadh 11451, Saudi Arabia
[6] King Saud Univ, Ctr Excellence Biotechnol Res CEBR, Riyadh, Saudi Arabia
[7] INTI Int Univ, Fac Hlth & Life Sci, Nilai 71800, Negeri Sembilan, Malaysia
关键词
HETEROJUNCTION; DEGRADATION;
D O I
10.1063/5.0213551
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, pure and S-N/WO3 (1%-7%) nanoparticles (NPs) have been developed for the degradation of MB dye. Optical properties, vibrational analysis, morphology, structural analysis, and photocatalytic activity of the samples have been evaluated using a variety of characterization techniques, including UV-vis, PL, FTIR, SEM, and x-ray diffraction (XRD). The XRD patterns showed that the stability of the orthorhombic phase of WO3 was affected by the concentrations of S and N. In SEM, nanospheres with an average size of 80 nm of NPs have been observed. The PL results showed that the e(-), h(+) recombination rate for the S-N-7%/WO3 sample was the lowest. The degradation of MB dye has also been investigated in order to investigate the photocatalytic performance. Remarkably, S-N-7%/WO3 shows the best results, with a maximum degradation of 90% in 120 min. The stability of the improved catalyst was tested using recycling and trapping studies. S-N-7%/WO3 catalyst's exceptional photocatalytic activity highlights its potential use in wastewater treatment. This study will be helpful for manufacturing innovation.
引用
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页数:10
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