Pressure-Compensated Fiber-Optic Photoacoustic Sensors for Trace SO2 Analysis in Gas Insulation Equipment

被引:12
|
作者
Zhao, Xinyu [1 ]
Zhang, Yajie [1 ]
Han, Xiao [1 ]
Qi, Hongchao [1 ]
Ma, Fengxiang [2 ]
Chen, Ke [1 ]
机构
[1] Dalian Univ Technol, Sch Optoelect Engn & Instrumentat Sci, Dalian 116024, Liaoning, Peoples R China
[2] Net Anhui Elect Power Co Ltd, Elect Power Res Inst, Hefei 230601, Anhui, Peoples R China
关键词
SPECTROSCOPY; SYSTEM; LASER; CELL;
D O I
10.1021/acs.analchem.4c01480
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A high-sensitivity fiber-optic photoacoustic sensor with pressure compensation is proposed to analyze the decomposition component SO2 in high-pressure gas insulation equipment. The multiple influence mechanism of pressure on photoacoustic excitation and cantilever detection has been theoretically analyzed and verified. In the high-pressure environment, the excited photoacoustic signal is enhanced, which compensates for the loss of sensitivity of the cantilever. A fiber-optic F-P cantilever is utilized to simultaneously measure static pressure and dynamic photoacoustic wave, and a spectral demodulation method based on white light interference is applied to calculate the optical path difference of the F-P interferometer (FPI). The real-time pressure is judged through the linear relationship between the average optical path difference of FPI and the pressure, which gives the proposed fiber-optic photoacoustic sensor the inherent advantages of being uncharged and resistant to electromagnetic interference. The average optical path difference of FPI is positively related to pressure, with a responsivity of 0.6 mu m/atm, which is based on changes in the refractive index of gas. In the range of 1-4 atm, the SO2 sensor has a higher detection sensitivity at high-pressure, which benefits from the pressure compensation effect. With the pressure environment of gas insulation equipment at 4 atm as the application background, the SO2 gas is tested. The detection limit is 20 ppb with an averaging time of 400 s.
引用
收藏
页码:10995 / 11001
页数:7
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