Nanotip-induced electric field for electrocatalysis

被引：2

作者：

Zhou, Kai ^{[1
]}

Li, Le ^{[2
]}

机构：

[1] Changzhou Vocat Inst Ind Technol, Sch Mat Engn, Changzhou 213164, Peoples R China

[2] Jiangsu Urban & Rural Construct Vocat Coll, Changzhou 213147, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2024年 / 1002卷

关键词：

Nanotip; Electric field Tip effect; Energy conversion; Electrocatalysis; CARBON-DIOXIDE REDUCTION; CO2; REDUCTION; EVOLUTION; SITES; NANOPARTICLES; NANOSHEETS; WATER;

D O I：

10.1016/j.jallcom.2024.175549

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The application of nanotip-induced local electric fields has been demonstrated to effectively tailor the microenvironment and electrochemical properties of catalysts, sparking significant interest in this field. Modifying the electronic structure at active sites, enhancing the concentration of electrolytes and reactants nearby the active center, and leveraging the strong proximity effect generated by the nanotip-induced local electric field have resulted in notable enhancements in electrocatalytic activity, selectivity, and durability. This review offers a comprehensive and structured overview of the latest progress in harnessing the tip effect in electrocatalysis, emphasizing the advantages of the local electric field influenced by the tip effect. Furthermore, it delves into the fundamental principles and origins of the electric field induced by the tip effect. Detailed conversations on applying these principles to enhance the electrocatalytic performance are also provided. The purpose of this review is to present researchers with a fresh concept and direction for further elevating electrocatalytic performance.

引用

页数：17

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