Nitrogen and oxygen self-doped hierarchical porous carbon nanosheets derived from turmeric leaves for high-performance supercapacitor

被引:4
|
作者
Chakraborty, Rishika [1 ]
Sharma, Avinash [2 ]
Maji, Pradip K. [3 ]
Rudra, Siddheswar [1 ]
Nayak, Arpan Kumar [4 ]
Chatterjee, Paresh Nath [5 ]
Banothu, Yadagiri Naik [6 ]
Pradhan, Mukul [2 ]
机构
[1] Natl Inst Technol Meghalaya, Dept Chem, Shillong 793003, Meghalaya, India
[2] Natl Inst Technol Warangal, Dept Chem, Warangal 506004, Telangana, India
[3] Indian Inst Technol Roorkee, Dept Polymer & Proc Engn, Saharanpur Campus, Saharanpur 247001, Uttar Pradesh, India
[4] Konkuk Univ, Dept Energy Engn, 120 Neungdong Ro, Seoul 05029, South Korea
[5] Natl Inst Technol Durgapur, Dept Chem Engn, Mahatma Gandhi Ave, Durgapur 713209, West Bengal, India
[6] Minist Def, DRDO Young Scientists Lab Smart Mat, Hyderabad 500058, India
关键词
Biomass; Chemical activation; Nanocarbon; Dual heteroatoms; Clean energy; Sustainable chemistry; ELECTRODE; SPHERE;
D O I
10.1016/j.ica.2024.122056
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
It is a formidable challenge to develop efficient and low-cost nanostructured carbonaceous materials for electrochemical energy storage application. Herein, a hierarchical porous carbon nanosheet is successfully synthesized in a facile manner from turmeric leaves by a two-step chemical activation strategy using KOH activator. The biomass-derived interconnected two-dimensional (2D) carbon framework prepared at 900 degrees C presents high selfdoped N (11.42 at%) and O contents (7.77 at%) together with specific surface area and pore volume of 541 m2/g and 0.47 cm3 g-1, respectively. Consequently, the resultant electroactive functional material shows a specific capacitance of 389 and 310 F/g at a current density of 1 A/g in acidic and neutral electrolytes, respectively. Additionally, an assembled symmetric supercapacitor device in Na2SO4 electrolyte delivers good capacitance retention of 90 % after 5000 consecutive charge-discharge cycles along with high specific energy (39.44 Wh kg- 1 at specific power of 0.49 kW kg- 1). This work provides a cost-effective, eco-friendly and sustainable outlook to prepare high-valued porous carbons from reliable biomass sources for high-performance supercapacitor application.
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页数:11
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