Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands

被引：482

作者：

Chen, Hao ^{[1
,2
]}

Liu, Cheng ^{[1
]}

Xu, Jian ^{[2
]}

Maxwell, Aidan ^{[2
]}

Zhou, Wei ^{[3
]}

Yang, Yi ^{[1
]}

Zhou, Qilin ^{[3
]}

Bati, Abdulaziz S. R. ^{[1
]}

Wan, Haoyue ^{[2
]}

Wang, Zaiwei ^{[2
]}

Zeng, Lewei ^{[2
]}

Wang, Junke ^{[2
]}

Serles, Peter ^{[4
]}

Liu, Yuan ^{[1
]}

Teale, Sam ^{[2
]}

Liu, Yanjiang ^{[2
]}

Saidaminov, Makhsud I. ^{[5
]}

Li, Muzhi ^{[6
]}

Rolston, Nicholas ^{[6
]}

Hoogland, Sjoerd ^{[2
]}

Filleter, Tobin ^{[4
]}

Kanatzidis, Mercouri G. ^{[1
]}

Chen, Bin ^{[1
]}

Ning, Zhijun ^{[3
]}

Sargent, Edward H. ^{[1
,2
,7
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Univ Toronto, Dept Elect & Comp Engn, Toronto, ON M5S 1A4, Canada

[3] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai, Peoples R China

[4] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada

[5] Univ Victoria, Dept Elect & Comp Engn, Victoria, BC V8P 5C2, Canada

[6] Arizona State Univ, Ira A Fulton Sch Engn, Tempe, AZ 85281 USA

[7] Northwestern Univ, Dept Elect & Comp Engn, Evanston, IL 60208 USA

来源：

SCIENCE | 2024年 / 384卷 / 6692期

关键词：

EFFICIENT; FILMS;

D O I：

10.1126/science.adm9474

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Inverted (pin) perovskite solar cells (PSCs) afford improved operating stability in comparison to their nip counterparts but have lagged in power conversion efficiency (PCE). The energetic losses responsible for this PCE deficit in pin PSCs occur primarily at the interfaces between the perovskite and the charge-transport layers. Additive and surface treatments that use passivating ligands usually bind to a single active binding site: This dense packing of electrically resistive passivants perpendicular to the surface may limit the fill factor in pin PSCs. We identified ligands that bind two neighboring lead(II) ion (Pb2+) defect sites in a planar ligand orientation on the perovskite. We fabricated pin PSCs and report a certified quasi-steady state PCE of 26.15 and 24.74% for 0.05- and 1.04-square centimeter illuminated areas, respectively. The devices retain 95% of their initial PCE after 1200 hours of continuous 1 sun maximum power point operation at 65 degrees C.

引用

页码：189 / 193

页数：5

共 54 条

[1] Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction [J].

Al-Ashouri, Amran ;

Kohnen, Eike ;

Li, Bor ;

Magomedov, Artiom ;

Hempel, Hannes ;

Caprioglio, Pietro ;

Marquez, Jose A. ;

Vilches, Anna Belen Morales ;

Kasparavicius, Ernestas ;

Smith, Joel A. ;

Phung, Nga ;

Menzel, Dorothee ;

Grischek, Max ;

Kegelmann, Lukas ;

Skroblin, Dieter ;

Gollwitzer, Christian ;

Malinauskas, Tadas ;

Jost, Marko ;

Matic, Gasper ;

Rech, Bernd ;

Schlatmann, Rutger ;

Topic, Marko ;

Korte, Lars ;

Abate, Antonio ;

Stannowski, Bernd ;

Neher, Dieter ;

Stolterfoht, Martin ;

Unold, Thomas ;

Getautis, Vytautas ;

Albrecht, Steve .

SCIENCE, 2020, 370 (6522) :1300-+

[2] Imaging and quantifying non-radiative losses at 23% efficient inverted perovskite solar cells interfaces [J].

Cacovich, Stefania ;

Vidon, Guillaume ;

Degani, Matteo ;

Legrand, Marie ;

Gouda, Laxman ;

Puel, Jean-Baptiste ;

Vaynzof, Yana ;

Guillemoles, Jean-Francois ;

Ory, Daniel ;

Grancini, Giulia .

NATURE COMMUNICATIONS, 2022, 13 (01)

[3] How Stable Is the 2D/3D Interface of Metal Halide Perovskite under Light and Heat? [J].

Chakkamalayath, Jishnudas ;

Hiott, Nathaniel ;

Kamat, Prashant V. .

ACS ENERGY LETTERS, 2023, 8 (01) :169-171

[4] Passivation of the Buried Interface via Preferential Crystallization of 2D Perovskite on Metal Oxide Transport Layers [J].

Chen, Bin ;

Chen, Hao ;

Hou, Yi ;

Xu, Jian ;

Teale, Sam ;

Bertens, Koen ;

Chen, Haijie ;

Proppe, Andrew ;

Zhou, Qilin ;

Yu, Danni ;

Xu, Kaimin ;

Vafaie, Maral ;

Liu, Yuan ;

Dong, Yitong ;

Jung, Eui Hyuk ;

Zheng, Chao ;

Zhu, Tong ;

Ning, Zhijun ;

Sargent, Edward H. .

ADVANCED MATERIALS, 2021, 33 (41)

[5] Regulating surface potential maximizes voltage in all-perovskite tandems [J].

Chen, Hao ;

Maxwell, Aidan ;

Li, Chongwen ;

Teale, Sam ;

Chen, Bin ;

Zhu, Tong ;

Ugur, Esma ;

Harrison, George ;

Grater, Luke ;

Wang, Junke ;

Wang, Zaiwei ;

Zeng, Lewei ;

Park, So Min ;

Chen, Lei ;

Serles, Peter ;

Awni, Rasha Abbas ;

Subedi, Biwas ;

Zheng, Xiaopeng ;

Xiao, Chuanxiao ;

Podraza, Nikolas J. ;

Filleter, Tobin ;

Liu, Cheng ;

Yang, Yi ;

Luther, Joseph M. ;

De Wolf, Stefaan ;

Kanatzidis, Mercouri G. ;

Yan, Yanfa ;

Sargent, Edward H. .

NATURE, 2023, 613 (7945) :676-+

[6] Quantum-size-tuned heterostructures enable efficient and stable inverted perovskite solar cells [J].

Chen, Hao ;

Teale, Sam ;

Chen, Bin ;

Hou, Yi ;

Grater, Luke ;

Zhu, Tong ;

Bertens, Koen ;

Park, So Min ;

Atapattu, Harindi R. ;

Gao, Yajun ;

Wei, Mingyang ;

Johnston, Andrew K. ;

Zhou, Qilin ;

Xu, Kaimin ;

Yu, Danni ;

Han, Congcong ;

Cui, Teng ;

Jung, Eui Hyuk ;

Zhou, Chun ;

Zhou, Wenjia ;

Proppe, Andrew H. ;

Hoogland, Sjoerd ;

Laquai, Frederic ;

Filleter, Tobin ;

Graham, Kenneth R. ;

Ning, Zhijun ;

Sargent, Edward H. .

NATURE PHOTONICS, 2022, 16 (05) :352-+

[7] Efficient and Stable Inverted Perovskite Solar Cells Incorporating Secondary Amines [J].

Chen, Hao ;

Wei, Qi ;

Saidaminov, Makhsud, I ;

Wang, Fei ;

Johnston, Andrew ;

Hou, Yi ;

Peng, Zijian ;

Xu, Kaimin ;

Zhou, Wenjia ;

Liu, Zhenghao ;

Qiao, Lu ;

Wang, Xiao ;

Xu, Siwen ;

Li, Jiangyu ;

Long, Run ;

Ke, Youqi ;

Sargent, Edward H. ;

Ning, Zhijun .

ADVANCED MATERIALS, 2019, 31 (46)

[8] Sulfonate-Assisted Surface Iodide Management for High-Performance Perovskite Solar Cells and Modules [J].

Chen, Ruihao ;

Wang, Yongke ;

Nie, Siqing ;

Shen, Hui ;

Hui, Yong ;

Peng, Jian ;

Wu, Binghui ;

Yin, Jun ;

Li, Jing ;

Zheng, Nanfeng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (28) :10624-10632

[9] Iodine reduction for reproducible and high-performance perovskite solar cells and modules [J].

Chen, Shangshang ;

Xiao, Xun ;

Gu, Hangyu ;

Huang, Jinsong .

SCIENCE ADVANCES, 2021, 7 (10)

[10] Recent Progresses on Defect Passivation toward Efficient Perovskite Solar Cells [J].

Gao, Feng ;

Zhao, Yang ;

Zhang, Xingwang ;

You, Jingbi .

ADVANCED ENERGY MATERIALS, 2020, 10 (13)

← 1 2 3 4 5 6 →