Tunable solvents: Shades of green

被引：48

作者：

Abou-Shehada, Sarah ^{[1
]}

Clark, James H. ^{[1
]}

Paggiola, Giulia ^{[1
]}

Sherwood, James ^{[1
]}

机构：

[1] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION | 2016年 / 99卷

关键词：

Tunable solvent; Distillation; Green solvent; Supercritical fluid; CATALYTIC OLEFIN HYDROFORMYLATION; LIFE-CYCLE ASSESSMENT; GAS-EXPANDED LIQUIDS; CARBON-DIOXIDE; SUPERCRITICAL FLUIDS; ENVIRONMENTAL ASSESSMENT; PHASE-BEHAVIOR; ETHYL LACTATE; IONIC LIQUID; PRESSURE;

D O I：

10.1016/j.cep.2015.07.005

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Research into the synthesis and application of green solvents is a developing field of interest relevant to a variety of chemical manufacturers. Tunable solvents utilising carbon dioxide lend themselves to a reduction in work-up solvent and can help avoid the need for energy intensive solvent recovery options such as distillation. This perspective examines the potential beneflts of tunable solvents to the chemical manufacturing industry and the environment. Freed from the usual reliance on distillation, high boiling solvents with an inherently lessened potential to cause air emissions can be used as part of a tunable solvent system. The application of bio-based solvents as tunable reaction media is highlighted as an area for further development. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：88 / 96

页数：9

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