Transition-metal-like coordination chemistry of dicoordinate borylenes with organic azides

被引：3

作者：

Witte, Robert ^{[1
,2
]}

Kar, Sourav ^{[1
,2
]}

Radacki, Krzysztof ^{[1
,2
]}

Haerterich, Marcel ^{[1
,2
]}

Rang, Maximilian ^{[1
,2
]}

Michel, Maximilian ^{[1
,2
]}

Mihm, Cornelius ^{[1
,2
]}

Czernetzki, Corinna ^{[1
,2
]}

Brueckner, Tobias ^{[1
,2
]}

Beck, Eva ^{[1
,2
]}

Lutz, Sarah ^{[1
,2
]}

Dewhurst, Rian D. ^{[1
,2
]}

Braunschweig, Holger ^{[1
,2
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany

[2] Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 65期

关键词：

BN ISOSTERES; COMPLEXES; MECHANISM; LIGANDS; CO;

D O I：

10.1039/d4cc02923b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolytic or oxidative liberation of a cyclic (amino)(alkyl)carbene (CAAC)-stabilized arylborylene in the presence of organoazides yielded borylene-organoazide complexes (4a,b) has been achieved in a manner akin to the first step of the Staudinger reaction. Similarly, a CAAC-stabilized aminoborylene also afforded borylene-organoazide complexes (6a-c), which further undergo rearrangement to produce aminoborane triazene species (7a,b). A series of borylene-organoazide complexes have been synthesized from the reactions of dicoordinate borylenes and organoazides.

引用

页码：8629 / 8632

页数：4

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