Transition-metal-like coordination chemistry of dicoordinate borylenes with organic azides

被引：3

作者：

Witte, Robert ^{[1
,2
]}

Kar, Sourav ^{[1
,2
]}

Radacki, Krzysztof ^{[1
,2
]}

Haerterich, Marcel ^{[1
,2
]}

Rang, Maximilian ^{[1
,2
]}

Michel, Maximilian ^{[1
,2
]}

Mihm, Cornelius ^{[1
,2
]}

Czernetzki, Corinna ^{[1
,2
]}

Brueckner, Tobias ^{[1
,2
]}

Beck, Eva ^{[1
,2
]}

Lutz, Sarah ^{[1
,2
]}

Dewhurst, Rian D. ^{[1
,2
]}

Braunschweig, Holger ^{[1
,2
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany

[2] Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 65期

关键词：

BN ISOSTERES; COMPLEXES; MECHANISM; LIGANDS; CO;

D O I：

10.1039/d4cc02923b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolytic or oxidative liberation of a cyclic (amino)(alkyl)carbene (CAAC)-stabilized arylborylene in the presence of organoazides yielded borylene-organoazide complexes (4a,b) has been achieved in a manner akin to the first step of the Staudinger reaction. Similarly, a CAAC-stabilized aminoborylene also afforded borylene-organoazide complexes (6a-c), which further undergo rearrangement to produce aminoborane triazene species (7a,b). A series of borylene-organoazide complexes have been synthesized from the reactions of dicoordinate borylenes and organoazides.

引用

页码：8629 / 8632

页数：4

共 40 条

[1] New cage compounds: Preparation and characterization of chiral C-3-symmetric macrobicyclic tris(phosphazides)
Alajarin, M
Molina, P
LopezLazaro, A
FocesFoces, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2): : 67 - 70
[2] Borane Adducts of Hydrazoic Acid and Organic Azides: Intermediates for the Formation of Aminoboranes
Blaesing, Kevin
Bresien, Jonas
Labbow, Rene
Michalik, Dirk
Schulz, Axel
Thomas, Max
Villinger, Alexander
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (20) : 6540 - 6544
[3] Organic azides:: An exploding diversity of a unique class of compounds
Bräse, S
Gil, C
Knepper, K
Zimmermann, V
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (33) : 5188 - 5240
[4] Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron
Braunschweig, Holger
Krummenacher, Ivo
Legare, Marc-Andre
Matler, Alexander
Radacki, Krzysztof
Ye, Qing
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) : 1802 - 1805
[5] Multiple complexation of CO and related ligands to a main-group element
Braunschweig, Holger
Dewhurst, Rian D.
Hupp, Florian
Nutz, Marco
Radacki, Krzysztof
Tate, Christopher W.
Vargas, Alfredo
Ye, Qing
[J]. NATURE, 2015, 522 (7556) : 327 - 330
[6] Formation of BN Isosteres of Azo Dyes by Ring Expansion of Boroles with Azides
Braunschweig, Holger
Celik, Mehmet Ali
Hupp, Florian
Krummenacher, Ivo
Mailaender, Lisa
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (21) : 6347 - 6351
[7] The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene-Alkyne Adducts
Braunschweig, Holger
Ewing, William C.
Geetharani, K.
Schaefer, Marius
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (05) : 1662 - 1665
[8] Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
Dahcheh, Fatme
Martin, David
Stephan, Douglas W.
Bertrand, Guy
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (48) : 13159 - 13163
[9] Towards the catalytic activation of inert small molecules by main-group ambiphiles
Dewhurst, Rian D.
Legare, Marc-Andre
Braunschweig, Holger
[J]. COMMUNICATIONS CHEMISTRY, 2020, 3 (01)
[10] Copper and sliver complexes containing organic azide ligands:: Syntheses, structures, and theoretical investigation of [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) and [HB(3,5-(CF3)2Pz)3]AgN(1-Ad)NN (where Pz = pyrazolyl and 1-Ad=1-adamantyl)
Dias, HVR
Polach, SA
Goh, SK
Archibong, EF
Marynick, DS
[J]. INORGANIC CHEMISTRY, 2000, 39 (17) : 3894 - 3901

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