Deville rebooted - practical N2O5 synthesis

被引：0

作者：

Edwards, Lee ^{[1
]}

Kariuki, Benson M. ^{[1
]}

Didsbury, Matthew ^{[2
]}

Jones, Christopher D. ^{[3
]}

Wirth, Thomas ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales

[2] BAE Syst Land UK, Glascoed NP15 1XL, Mons, Wales

[3] Falcon Project Ltd, Magazine Area, Westcott Venture Pk, Aylesbury HP18 0XB, England

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 46期

关键词：

DINITROGEN PENTOXIDE; NITRATION;

D O I：

10.1039/d4cc01403k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dinitrogen pentoxide (N2O5), the anhydride of nitric acid, was synthesised by Henri & Eacute;tienne Sainte-Claire Deville in Paris in 1849 using silver nitrate and chlorine gas. Herein, we revisit, optimise, and modify Deville's method using photocatalysis to enable a safe, clean, practical, and reproducible alternative for N2O5 synthesis in quantitative yields. Moreover, it is predicted that the modifications can accommodate an industrial scale-up, but the silver chloride generated must be recycled.

引用

页码：5920 / 5923

页数：4

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