Deville rebooted - practical N2O5 synthesis

被引：0
作者：
Edwards, Lee [1 ]
Kariuki, Benson M. [1 ]
Didsbury, Matthew [2 ]
Jones, Christopher D. [3 ]
Wirth, Thomas [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
[2] BAE Syst Land UK, Glascoed NP15 1XL, Mons, Wales
[3] Falcon Project Ltd, Magazine Area, Westcott Venture Pk, Aylesbury HP18 0XB, England
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 46期
关键词：
DINITROGEN PENTOXIDE; NITRATION;
D O I：
10.1039/d4cc01403k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dinitrogen pentoxide (N2O5), the anhydride of nitric acid, was synthesised by Henri & Eacute;tienne Sainte-Claire Deville in Paris in 1849 using silver nitrate and chlorine gas. Herein, we revisit, optimise, and modify Deville's method using photocatalysis to enable a safe, clean, practical, and reproducible alternative for N2O5 synthesis in quantitative yields. Moreover, it is predicted that the modifications can accommodate an industrial scale-up, but the silver chloride generated must be recycled.
引用
收藏
页码：5920 / 5923
页数：4
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