Synthesis of Sb2Se3 @PPy nanorod composite as cathode material for aluminum batteries

被引:4
|
作者
Li, Jian [1 ]
Luo, Wenbin [1 ]
Ou, Jinfeng [1 ]
Yu, Yi [1 ]
Zhang, Zhen [1 ]
Chao, Zisheng [1 ]
Fan, Jincheng [1 ]
Yi, Wenjun [1 ]
Wang, Yadong [2 ]
机构
[1] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
关键词
Aluminum batteries; Cathode; Nanorod; Electrochemical performance; ION BATTERIES; ANODE; ELECTROCATALYSTS;
D O I
10.1016/j.apsusc.2024.160324
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Aluminum batteries (ABs) are a promising alternative to lithium-ion batteries (LIBs) in the future. The development of aluminum batteries (ABs) is closely related to their cathode material. In this paper, we successfully designed and prepared a nanorod structure Sb2Se3@PPy as cathode material for ABs. It exhibits a high reversible capacity of 302 mAh/g at 0.2 A/g, and the capacity is maintained at about 210 mAh/g after 50 cycles. In addition, the electrochemical reaction mechanism and kinetic process of Sb2Se3@PPy were studied. The results showed that the PPy coating layer reduced the volume change of Sb2Se3, prevented irreversible deformation, enhanced the structural stability and electronic conductivity.
引用
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页数:8
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