Catalytic transformation of plastic waste: Harnessing zeolite for enhanced energy product yield in pyrolysis

被引:11
作者
Belrhazi, Ilyass [1 ,2 ]
Sair, Said [1 ]
Ousaleh, Hanane Ait [3 ]
Abdellaoui, Youness [4 ]
Zahouily, Mohamed [1 ,2 ]
机构
[1] Mohammed VI Polytech Univ UM6P, MAScIR Fdn, VARENA Ctr, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco
[2] Hassan II Univ, Fac Sci & Technol, Lab Mat Catalysis & Valorizat Nat Resources, URAC 24, BP 146, Casablanca, Morocco
[3] Mohammed VI Polytech Univ UM6P, Lab Inorgan Mat Sustainable Energy Technol, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco
[4] CONAHCyT Cinvestav Saltillo, Sustentabilidad Recursos Nat & Energia, Ave Ind Met 1062,Parque Ind Ramos Arizpe, Ramos Arizpe 25900, Coahuila, Mexico
关键词
Plastic feedstock; Catalytic pyrolysis; Zeolite catalyst; High-energy products; Theoretical analysis; HIGH-DENSITY POLYETHYLENE; THERMAL-DEGRADATION; AROMATIC-HYDROCARBONS; CO-PYROLYSIS; KINETICS; POLYPROPYLENE; CRACKING; BEHAVIORS; RANGE; FTIR;
D O I
10.1016/j.enconman.2024.118897
中图分类号
O414.1 [热力学];
学科分类号
摘要
Addressing the significant environmental challenge posed by plastic waste demands innovative approaches to its management and conversion into sustainable resources. Catalytic pyrolysis emerges as a promising solution, offering a method to transform plastic waste into high-energy products and contributing to environmental remediation efforts. The study aims to synthesize and characterize the P-zeolite catalyst and assess its influence on the pyrolysis process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) were employed to investigate catalyst structure and properties. Catalytic pyrolysis experiments are conducted using TGA to simulate the process of plastic decomposition and pyrolysis. Additionally, a range of parameters including temperature, catalyst amount, and reaction activation energy have been investigated through both experimental and theoretical analyses. The results demonstrated the pivotal role of the 10 % of synthesized zeolite catalyst in reducing temperature requirements and activation energy by 100 degrees C and 118 kJ/mol, respectively, compared to thermal pyrolysis conducted without the use of a catalyst.
引用
收藏
页数:12
相关论文
共 54 条
[1]   Thermal degradation behaviors of polyethylene and polypropylene. Part I: Pyrolysis kinetics and mechanisms [J].
Aboulkas, A. ;
El Harfi, K. ;
El Bouadili, A. .
ENERGY CONVERSION AND MANAGEMENT, 2010, 51 (07) :1363-1369
[2]  
Almeida D, 2016, POLIMEROS, V26, P44
[3]   Experimental Study of Thermal and Catalytic Pyrolysis of Plastic Waste Components [J].
Anene, Azubuike Francis ;
Fredriksen, Siw Bodil ;
Saetre, Kai Arne ;
Tokheim, Lars-Andre .
SUSTAINABILITY, 2018, 10 (11)
[4]   Petrochemical feedstock by thermal cracking of plastic waste [J].
Angyal, Andras ;
Miskolczi, Norbert ;
Bartha, Laszlo .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2007, 79 (1-2) :409-414
[5]  
Arrhenius S., 1889, Z. Phys. Chem., V4, P226, DOI DOI 10.1515/ZPCH-1889-0416
[6]   Chemical activation of a kaolinite under acid and alkaline conditions [J].
Belver, C ;
Muñoz, MAB ;
Vicente, MA .
CHEMISTRY OF MATERIALS, 2002, 14 (05) :2033-2043
[7]   High Density Polyethylene Degradation Followed by Closed-loop Recycling [J].
Benoit, Nathalie ;
Gonzalez-Nunez, Ruben ;
Rodrigue, Denis .
PROGRESS IN RUBBER PLASTICS AND RECYCLING TECHNOLOGY, 2017, 33 (01) :17-37
[8]  
Beyene Hayelom Dargo., 2014, International Journal of Science, Technology and Society, V2, P190, DOI DOI 10.11648/J.IJSTS.20140206.15
[9]   Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk [J].
Cai, Junmeng ;
Xu, Di ;
Dong, Zhujun ;
Yu, Xi ;
Yang, Yang ;
Banks, Scott W. ;
Bridgwater, Anthony V. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2018, 82 :2705-2715
[10]  
Calvert PD, 1986, Br Polym J, P278