Engineering Bimetallic Active Sites in Metal-Organic Frameworks: Challenges and Opportunities

被引：4
作者：
Geary, Jackson [1 ]
Xiao, Dianne J. [1 ]
机构：
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
来源：
CHEMISTRY OF MATERIALS | 2024年 / 36卷 / 10期
基金：
美国国家科学基金会;
关键词：
ATOMIC LAYER DEPOSITION; CARBON-DIOXIDE; CATALYSIS; MOF; OXIDATION; CONSTRUCTION; ADSORPTION; STABILITY; COMPLEXES; REDUCTION;
D O I：
10.1021/acs.chemmater.3c03129
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Examples of two metal centers working synergistically to catalyze challenging chemical transformations can be found throughout biological and synthetic systems. In each case, specific metal identities, ligand environments, and metal-metal distances are required. The structural precision needed to engineer a productive, surface-supported bimetallic active site represents an opportunity for metal-organic frameworks. In this perspective, we summarize the different ways binuclear metal active sites have been synthesized in metal-organic frameworks and applied in catalysis. Selected examples from the literature will be highlighted to illustrate both the diversity of synthetic approaches as well as the diversity of bimetallic structures.
引用
收藏
页码：4916 / 4928
页数：13
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