Recent advances in metal-mediated oxidations with mCPBA

被引：4

作者：

Varala, Ravi ^{[1
,2
]}

Dhadda, Surbhi ^{[3
]}

Seema, Vittal ^{[4
]}

Amanullah, Mohammed ^{[5
]}

Hussien, Mohamed ^{[6
]}

Alam, Mohammed Mujahid ^{[6
]}

机构：

[1] Scrips Pharm, Hyderabad 500076, Telangana, India

[2] INTI Int Univ, Nilai 71800, Malaysia

[3] Vivekananda Global Univ, Fac Basic & Appl Sci, Dept Chem, Jaipur 303012, Rajashan, India

[4] RGUKT Basar, Dept Chem, Nirmal 504107, Telangana, India

[5] King Khalid Univ, Coll Med, Dept Clin Biochem, Abha, Saudi Arabia

[6] King Khalid Univ, Coll Sci, Dept Chem, Abha 61421, Saudi Arabia

来源：

TRANSITION METAL CHEMISTRY | 2024年 / 49卷 / 06期

关键词：

M-CHLOROPERBENZOIC ACID; C-H BONDS; M-CPBA; HYDROXYLATION; FUNCTIONALIZATION; COMPLEXES; CATALYSTS; OXIDANT; ALKANES;

D O I：

10.1007/s11243-024-00593-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Among the various peroxides that are available, meta-chloroperbenzoic acid (mCPBA) is an effective oxidizing reagent that is used in a variety of oxidative transformations, including rearrangements, oxidation of different functional groups, and the formation of carbon-carbon and carbon-heteroatom bonds. This mini-review aims to emphasize on properties, structures, and reactivities of intermediate species involved in the representative metal-assisted contributions of mCPBA in organic synthesis and catalysis along with its scope, merits, and demerits of the reaction from mid-2015 to date.

引用

页码：395 / 428

页数：34

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