Recent advances in metal-mediated oxidations with mCPBA

被引:1
作者
Varala, Ravi [1 ,2 ]
Dhadda, Surbhi [3 ]
Seema, Vittal [4 ]
Amanullah, Mohammed [5 ]
Hussien, Mohamed [6 ]
Alam, Mohammed Mujahid [6 ]
机构
[1] Scrips Pharm, Hyderabad 500076, Telangana, India
[2] INTI Int Univ, Nilai 71800, Malaysia
[3] Vivekananda Global Univ, Fac Basic & Appl Sci, Dept Chem, Jaipur 303012, Rajashan, India
[4] RGUKT Basar, Dept Chem, Nirmal 504107, Telangana, India
[5] King Khalid Univ, Coll Med, Dept Clin Biochem, Abha, Saudi Arabia
[6] King Khalid Univ, Coll Sci, Dept Chem, Abha 61421, Saudi Arabia
关键词
M-CHLOROPERBENZOIC ACID; C-H BONDS; M-CPBA; HYDROXYLATION; FUNCTIONALIZATION; COMPLEXES; CATALYSTS; OXIDANT; ALKANES;
D O I
10.1007/s11243-024-00593-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Among the various peroxides that are available, meta-chloroperbenzoic acid (mCPBA) is an effective oxidizing reagent that is used in a variety of oxidative transformations, including rearrangements, oxidation of different functional groups, and the formation of carbon-carbon and carbon-heteroatom bonds. This mini-review aims to emphasize on properties, structures, and reactivities of intermediate species involved in the representative metal-assisted contributions of mCPBA in organic synthesis and catalysis along with its scope, merits, and demerits of the reaction from mid-2015 to date.
引用
收藏
页码:395 / 428
页数:34
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