Hydrogenation of Alkynes to cis-Alkenes with Hydrazine in Air

被引：1
|
作者：
Wang, Jintao [1 ]
Xiong, Jiukai [1 ]
Li, juanjuan [1 ]
Wang, Jiali [1 ]
Wang, Kerang [1 ]
Li, Xiaoliu [1 ]
机构：
[1] Hebei Univ, Coll Chem & Environm Sci, Key Lab Med Chem & Mol Diag, Key Lab Chem Biol Hebei Prov,Minist Educ, Baoding 071002, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 37卷 / 06期
基金：
中国国家自然科学基金;
关键词：
transfer hydrogenation; hydrazine; alkynes; alkenes; diazene; CATALYZED AEROBIC REDUCTION; IN-SITU GENERATION; DIIMIDE; OLEFINS; EMISSION; OXYGEN;
D O I：
10.6023/cjoc201701040
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transfer hydrogenation is a mild and effective way in reduction reaction. In this paper, a simple approach of selectively hydrogenation of alkynes to cis-alkenes with NH2NH2 center dot H2O as a transfer hydrogenation agent in the presence of air without any catalysts or metals was developed. Furthermore, the configuration of cis-alkene was confirmed by the 2D NOESY spectrum.
引用
收藏
页码：1407 / 1411
页数：5
相关论文
共 30 条
  • [1] [Anonymous], 2007, The Handbook of Homogeneous Hydrogenation
  • [2] Chernichenko K, 2013, NAT CHEM, V5, P718, DOI [10.1038/NCHEM.1693, 10.1038/nchem.1693]
  • [3] Transfer Hydrogenation of Ethyl Levulinate to γ-Valerolactone Catalyzed by Iron Complexes
    Dai, Nan
    Shang, Rui
    Fu, Mingchen
    Fu, Yao
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2015, 33 (04) : 405 - 408
  • [4] Pilot Plant PAT Approach for the Diastereoselective Diimide Reduction of Artemisinic Acid
    Feth, Martin P.
    Rossen, Kai
    Burgard, Andreas
    [J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2013, 17 (02) : 282 - 293
  • [5] Continuous-Flow TechnologyA Tool for the Safe Manufacturing of Active Pharmaceutical Ingredients
    Gutmann, Bernhard
    Cantillo, David
    Kappe, C. Oliver
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (23) : 6688 - 6728
  • [6] Transfer semihydrogenation of alkynes catalyzed by a zero-valent palladium N-heterocyclic carbene complex
    Hauwert, Peter
    Maestri, Giovanni
    Sprengers, Jeroen W.
    Catellani, Marta
    Elsevier, Cornelis J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (17) : 3223 - 3226
  • [7] Mechanism of Pd(NHC)-Catalyzed Transfer Hydrogenation of Alkynes
    Hauwert, Peter
    Boerleider, Romilda
    Warsink, Stefan
    Weigand, Jan J.
    Elsevier, Cornelis J.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (47) : 16900 - 16910
  • [8] Bioinduced Room-Temperature Methanol Reforming
    Heim, Leo E.
    Thiel, Daniel
    Gedig, Christian
    Deska, Jan
    Prechtl, Martin H. G.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (35) : 10308 - 10312
  • [9] Synthesis, light emission, and photovoltaic properties of perylene-containing polyacetylenes
    Hua, Jianli
    Lam, Jacky Wing Yip
    Yu, Xiaoming
    Wu, Lijun
    Kwok, Hoi Sing
    Wong, Kam Sing
    Tang, Ben Zhong
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (06) : 2025 - 2037
  • [10] CHEMISTRY OF DIIMINE
    HUNIG, S
    MULLER, HR
    THIER, W
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (04) : 271 - &
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