Advanced Nanocarbons Toward two-Electron Oxygen Electrode Reactions for H2O2 Production and Integrated Energy Conversion

被引：0
|
作者：
Zhao, Linjie [1 ]
Yan, Riqing [1 ]
Mao, Baoguang [1 ]
Paul, Rajib [2 ]
Duan, Wenjie [1 ]
Dai, Liming [3 ]
Hu, Chuangang [1 ]
机构：
[1] Beijing Univ Chem Technol, Beijing Key Lab Energy Environm Catalysis, State Key Lab Organ Inorgan Composites, Coll Chem Engn, Beijing 100029, Peoples R China
[2] Kent State Univ, Adv Mat & Liquid Crystal Inst, Kent, OH 44242 USA
[3] Univ New South Wales, Australian Carbon Mat Ctr A CMC, Sch Chem Engn, Sydney, NSW 2052, Australia
来源：
SMALL | 2024年 / 20卷 / 43期
基金：
中国国家自然科学基金; 澳大利亚研究理事会;
关键词：
carbon-based metal-free electrochemical catalysts; hydrogen peroxide; integrated reactor design; two-electron oxygen reduction reaction; two-electron water oxidation reaction; NITROGEN-DOPED CARBON; HYDROGEN-PEROXIDE PRODUCTION; ASSISTED SYNTHESIS; ACTIVE-SITE; REDUCTION; ELECTROSYNTHESIS; ELECTROCATALYSTS; OXIDATION; GRAPHENE; CATALYST;
D O I：
10.1002/smll.202403029
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogen peroxide (H2O2) plays a pivotal role in advancing sustainable technologies due to its eco-friendly oxidizing capability. The electrochemical two-electron (2e(-)) oxygen reduction reaction and water oxidation reaction present an environmentally green method for H2O2 production. Over the past three years, significant progress is made in the field of carbon-based metal-free electrochemical catalysts (C-MFECs) for low-cost and efficient production of H2O2 (H2O2EP). This article offers a focused and comprehensive review of designing C-MFECs for H2O2EP, exploring the construction of dual-doping configurations, heteroatom-defect coupling sites, and strategic dopant positioning to enhance H2O2EP efficiency; innovative structural tuning that improves interfacial reactant concentration and promote the timely release of H2O2; modulation of electrolyte and electrode interfaces to support the 2e(-) pathways; and the application of C-MFECs in reactors and integrated energy systems. Finally, the current challenges and future directions in this burgeoning field are discussed.
引用
收藏
页数：19
相关论文
共 50 条
  • [21] BiOBr/COF S-scheme photocatalyst for H2O2 production via concerted two-electron pathway
    Zhang, Haozhen
    Liu, Jingjing
    Zhang, Yong
    Cheng, Bei
    Zhu, Bicheng
    Wang, Linxi
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2023, 166 : 241 - 249
  • [22] Electrosynthesis of H2O2 via two-electron oxygen reduction over carbon-based catalysts: From microenvironment control to electrode/reactor design
    Jia J.
    Li Z.
    Tian Y.
    Li X.
    Chen R.
    Liu J.
    Liang J.
    Energy Reviews, 2024, 3 (02):
  • [23] Electrocatalytic H2O2 production via two-electron O2 reduction by Mo-doped TiO2 nanocrystallines
    Deng, Zhiqin
    Ma, Chaoqun
    Yan, Shihai
    Liang, Jie
    Dong, Kai
    Li, Tingshuai
    Wang, Yan
    Yue, Luchao
    Luo, Yonglan
    Liu, Qian
    Liu, Yang
    Gao, Shuyan
    Du, Juan
    Sun, Xuping
    CATALYSIS SCIENCE & TECHNOLOGY, 2021, 11 (21) : 6970 - 6974
  • [24] Ultrafine Co nanoparticles confined in nitrogen-doped carbon toward two-electron oxygen reduction reaction for H2O2 electrosynthesis in acidic media
    Xiaoqing Cui
    Lijie Zhong
    Xu Zhao
    Jingxin Xie
    Dequan He
    Xin Yang
    Kanglong Lin
    Huan Wang
    Li Niu
    ChineseChemicalLetters, 2023, 34 (11) : 282 - 287
  • [25] Engineering Nonprecious Metal Oxides Electrocatalysts for Two-Electron Water Oxidation to H2O2
    Hu, Xin
    Sun, Zixu
    Mei, Guoliang
    Zhao, Xin
    Xia, Bao Yu
    You, Bo
    ADVANCED ENERGY MATERIALS, 2022, 12 (32)
  • [26] One- or Two-Electron Water Oxidation, Hydroxyl Radical, or H2O2 Evolution
    Siahrostami, Samira
    Li, Guo-Ling
    Viswanathan, Venkatasubramanian
    Norskov, Jens K.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (06): : 1157 - 1160
  • [27] Novel electrocatalyst with abundant oxygen vacancies enabling efficient two-electron water oxidation reaction for H2O2 synthesis
    Guta, Chemeda Barasa
    Edao, Habib Gemechu
    Dilebo, Woldesenbet Bafe
    Chang, Chia-Yu
    Angerasa, Fikiru Temesgen
    Moges, Endalkachew Asefa
    Nikodimos, Yosef
    Lakshmanan, Keseven
    Tsai, Meng-Che
    Su, Wei-Nien
    Hwang, Bing Joe
    CHEMICAL ENGINEERING JOURNAL, 2024, 500
  • [28] Enhanced Electrochemical H2O2 Production via Two-Electron Oxygen Reduction Enabled by Surface-Derived Amorphous Oxygen-Deficient TiO2-x
    Xu, Zhaoquan
    Liang, Jie
    Wang, Yuanyuan
    Dong, Kai
    Shi, Xifeng
    Liu, Qian
    Luo, Yonglan
    Li, Tingshuai
    Jia, Yu
    Asiri, Abdullah M.
    Feng, Zhesheng
    Wang, Yan
    Ma, Dongwei
    Sun, Xuping
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (28) : 33182 - 33187
  • [29] Effects of Sb2O3 polymorphism on the performances for electrocatalytic H2O2 production via the two-electron water oxidation reaction
    Guo, Wenlong
    Xie, Yinqiong
    Liu, Yaxin
    Shang, Shiyu
    Lian, Xin
    Liu, Xi
    APPLIED SURFACE SCIENCE, 2022, 606
  • [30] CaSnO3: An Electrocatalyst for Two-Electron Water Oxidation Reaction to Form H2O2
    Park, So Yeon
    Abroshan, Hadi
    Shi, Xinjian
    Jung, Hyun Suk
    Siahrostami, Samira
    Zheng, Xiaolin
    ACS ENERGY LETTERS, 2019, 4 (01) : 352 - 357
12345