Hybrid Nanocomposites Based on Poly(3,6-dianiline-2,5-dichloro-1,4-benzoquinone): Synthesis, Structure and Properties

被引:0
作者
Kiseleva, Svetlana G. [1 ]
Bondarenko, Galina N. [1 ]
Orlov, Andrey V. [1 ]
Muratov, Dmitriy G. [1 ]
Kozlov, Vladimir V. [1 ]
Vasilev, Andrey A. [1 ]
Karpacheva, Galina P. [1 ]
机构
[1] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, Leninsky pr 29, Moscow 119991, Russia
关键词
oxidative polymerization; dianilinedichlorobenzoquinone; graphene oxide; nanocomposites; REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE SUPERCAPACITOR; HYDROGEN-BONDING INTERACTIONS; IN-SITU; POLYANILINE; POLYMERIZATION; COMPOSITE; REDUCTION; CONDUCTIVITY; STABILITY;
D O I
10.3390/polym16131832
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hybrid nanocomposites based on poly(3,6-dianiline-2,5-dichloro-1,4-benzoquinone) (PDACB) in salt form and graphene oxide (GO) have been obtained for the first time, and the significant influence of the preparation method on the composition and structure of nanocomposites and their functional properties has been demonstrated. Nanocomposites were prepared in three ways: via ultrasonic mixing of PDACB and GO; via in situ oxidative polymerization of 3,6-dianiline-2,5-dichloro-1,4-benzoquinone (DACB) in the presence of GO; and by heating a suspension of previously prepared PDACB and GO in DMF with the removal of the solvent. The results of the study of the composition, chemical structure, morphology, thermal stability and electrical properties of nanocomposites obtained via various methods are presented. Nanocomposites obtained by mixing the components in an ultrasonic field demonstrated strong intermolecular interactions between PDACB and GO both due to the formation of hydrogen bonds and pi-stacking, as well as through electrostatic interactions. Under oxidative polymerization of DACB in the presence of GO, the latter participated in the oxidative process, being partially reduced. At the same time, a PDACB polymer film was formed on the surface of the GO. Prolonged heating for 4 h at 85 degrees C of a suspension of PDACB and GO in DMF led to the dedoping of PDACB with the transition of the polymer to the base non-conductive form and the reduction of GO. Regardless of the preparation method, all nanocomposites showed an increase in thermal stability compared to PDACB. All nanocomposites were characterized by a hopping mechanism of conductivity. Direct current (dc) conductivity sigma dc values varied within two orders of magnitude depending on the preparation conditions.
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共 96 条
  • [1] Composite materials based on reduced graphene oxide and polyaniline. Composition, morphology, electrochemical properties
    Abalyaeva, V. V.
    Baskakov, S. A.
    Dremova, N. N.
    [J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2015, 51 (10) : 916 - 924
  • [2] Abalyaeva V.V., 2018, Polym. Sci. Ser. B Chem, V60, P511, DOI [10.1134/S1560090418060015, DOI 10.1134/S1560090418060015]
  • [3] The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption Spectroscopy
    Acik, Muge
    Lee, Geunsik
    Mattevi, Cecilia
    Pirkle, Adam
    Wallace, Robert M.
    Chhowalla, Manish
    Cho, Kyeongjae
    Chabal, Yves
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (40) : 19761 - 19781
  • [4] The Role of Intercalated Water in Multilayered Graphene Oxide
    Acik, Muge
    Mattevi, Cecilia
    Gong, Cheng
    Lee, Geunsik
    Cho, Kyeongjae
    Chhowalla, Manish
    Chabal, Yves J.
    [J]. ACS NANO, 2010, 4 (10) : 5861 - 5868
  • [5] Modification of nanosized natural montmorillonite for ultrasound-enhanced adsorption of Acid Red 17
    Acisli, Ozkan
    Khataee, Alireza
    Karaca, Semra
    Sheydaei, Mohsen
    [J]. ULTRASONICS SONOCHEMISTRY, 2016, 31 : 116 - 121
  • [6] Electrochemistry of Graphene and Related Materials
    Ambrosi, Adriano
    Chua, Chun Kiang
    Bonanni, Alessandra
    Pumera, Martin
    [J]. CHEMICAL REVIEWS, 2014, 114 (14) : 7150 - 7188
  • [7] Synthesis of hybrid polyaniline – graphene oxide – sulfur nanocomposite fibers through ice nucleation as a cathode materials for lithium-sulfur battery
    Badi N.
    Roy A.S.
    Al-Aoh H.A.
    Alghamdi S.A.
    Alatawi A.S.
    Ignatiev A.
    [J]. Materials Science for Energy Technologies, 2023, 6 : 351 - 358
  • [8] Bagri A, 2010, NAT CHEM, V2, P581, DOI [10.1038/NCHEM.686, 10.1038/nchem.686]
  • [9] Effect of polyaniline content and protonating dopants on electroconductive composites
    Bednarczyk, Katarzyna
    Matysiak, Wiktor
    Tanski, Tomasz
    Janeczek, Henryk
    Schab-Balcerzak, Ewa
    Libera, Marcin
    [J]. SCIENTIFIC REPORTS, 2021, 11 (01)
  • [10] Effect of aromatic substitution in aniline on the properties of polyaniline
    Bhadra, Sambhu
    Singha, Nikhil K.
    Khastgir, Dipak
    [J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (06) : 1763 - 1770