Design of pH-universal electrocatalysts for hydrogen evolution reaction

被引：27

作者：

Lin, Jingwen ^{[1
]}

Wang, Xu ^{[1
]}

Zhao, Zhenyun ^{[1
]}

Chen, Dongliang ^{[1
]}

Liu, Rumin ^{[1
]}

Ye, Zhizhen ^{[1
,2
]}

Lu, Bin ^{[1
,2
]}

Hou, Yang ^{[3
]}

Lu, Jianguo ^{[1
,2
]}

机构：

[1] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon & Adv Semicond Mat, Hangzhou 310027, Peoples R China

[2] Zhejiang Univ, Inst Wenzhou, Wenzhou, Peoples R China

[3] Zhejiang Univ, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 315008, Peoples R China

来源：

CARBON ENERGY | 2024年 / 6卷 / 11期

关键词：

design strategy; hydrogen evolution reaction; pH-universal electrocatalysts; HIGHLY EFFICIENT CATALYSIS; TRANSITION-METAL CARBIDES; SINGLE-ATOM CATALYSTS; DOPED CARBON; BIFUNCTIONAL ELECTROCATALYSTS; SELENIDE ELECTROCATALYSTS; ROBUST ELECTROCATALYST; ACTIVE ELECTROCATALYST; RENEWABLE ENERGY; COBALT-BORIDE;

D O I：

10.1002/cey2.555

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The path to searching for sustainable energy has never stopped since the depletion of fossil fuels can lead to serious environmental pollution and energy shortages. Using water electrolysis to produce hydrogen has been proven to be a prioritized approach for green resource production. It is highly crucial to explore inexpensive and high-performance electrocatalysts for accelerating hydrogen evolution reaction (HER) and apply them to industrial cases on a large scale. Here, we summarize the different mechanisms of HER in different pH settings and review recent advances in non-noble-metal-based electrocatalysts. Then, based on the previous efforts, we discuss several universal strategies for designing pH-independent catalysts and show directions for the future design of pH-universal catalysts. A comprehensive and helpful tutorial is organized with a suitable discussion on the advanced mechanism as well as the universal assessment index of hydrogen evolution reaction. Additional summaries of current research on high-rate pH-all electrocatalysts and pertinent optimization techniques are also included. image

引用

页数：32

共 195 条

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