Toward practical lithium-sulfur batteries

被引:6
作者
Qian, Weiwei [1 ,2 ]
Guo, Yawei [1 ,3 ]
Zuo, Weijing [1 ]
Wu, Xiangkun [1 ]
Zhang, Lan [1 ]
机构
[1] Inst Proc Engn, Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
[2] Henan Univ, Zhengzhou Inst Emerging Ind Technol, Longzihu New Energy Lab, Zhengzhou 450000, Peoples R China
[3] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
基金
国家自然科学基金重大项目; 中国国家自然科学基金;
关键词
LI-S BATTERIES; ENERGY-DENSITY; ORGANOSULFUR COMPOUNDS; CATHODE MATERIAL; ELECTROLYTE; PERFORMANCE; SOLVENT; BINDER; CHEMISTRY; DESIGN;
D O I
10.1039/d4qm00180j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As one of the most promising energy-storage devices, lithium-sulfur batteries (LSBs) have been intensively studied and are currently on the edge of practical applications. Ampere hour (A h) level pouch cells are being prepared; however, they still face multiple challenges such as a low practical energy density, short cycle life, and underlying safety issues. The main reasons for these are due to the contradictions between the battery kinetics and electrolyte/sulfur (E/S) ratio, while the utilization of the metal lithium anode also raises possible dendrite concerns. In this review, we summarize the strategy to realize high-loading cathodes and a lean electrolyte for LSBs. In addition, solid-state LSBs are briefly discussed. Hopefully, this work may promote further advances in practical Li-S batteries. A cathode with an areal capacity of more than 5 mA h cm-2 is crucial for practical Li-S batteries. Besides, reducing the electrolyte weight ratio, in both liquid and solid-state Li-S batteries, is also important.
引用
收藏
页码:2556 / 2577
页数:22
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