Toward practical lithium-sulfur batteries

被引:10
作者
Qian, Weiwei [1 ,2 ]
Guo, Yawei [1 ,3 ]
Zuo, Weijing [1 ]
Wu, Xiangkun [1 ]
Zhang, Lan [1 ]
机构
[1] Inst Proc Engn, Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
[2] Henan Univ, Zhengzhou Inst Emerging Ind Technol, Longzihu New Energy Lab, Zhengzhou 450000, Peoples R China
[3] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
基金
国家自然科学基金重大项目; 中国国家自然科学基金;
关键词
LI-S BATTERIES; ENERGY-DENSITY; ORGANOSULFUR COMPOUNDS; CATHODE MATERIAL; ELECTROLYTE; PERFORMANCE; SOLVENT; BINDER; CHEMISTRY; DESIGN;
D O I
10.1039/d4qm00180j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As one of the most promising energy-storage devices, lithium-sulfur batteries (LSBs) have been intensively studied and are currently on the edge of practical applications. Ampere hour (A h) level pouch cells are being prepared; however, they still face multiple challenges such as a low practical energy density, short cycle life, and underlying safety issues. The main reasons for these are due to the contradictions between the battery kinetics and electrolyte/sulfur (E/S) ratio, while the utilization of the metal lithium anode also raises possible dendrite concerns. In this review, we summarize the strategy to realize high-loading cathodes and a lean electrolyte for LSBs. In addition, solid-state LSBs are briefly discussed. Hopefully, this work may promote further advances in practical Li-S batteries. A cathode with an areal capacity of more than 5 mA h cm-2 is crucial for practical Li-S batteries. Besides, reducing the electrolyte weight ratio, in both liquid and solid-state Li-S batteries, is also important.
引用
收藏
页码:2556 / 2577
页数:22
相关论文
共 183 条
[81]   Lithiated metallic molybdenum disulfide nanosheets for high-performance lithium-sulfur batteries [J].
Li, Zhuangnan ;
Sami, Ismail ;
Yang, Jieun ;
Li, Juntao ;
Kumar, Ramachandran Vasant ;
Chhowalla, Manish .
NATURE ENERGY, 2023, 8 (01) :84-93
[82]   Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery [J].
Liang, Chengdu ;
Dudney, Nancy J. ;
Howe, Jane Y. .
CHEMISTRY OF MATERIALS, 2009, 21 (19) :4724-4730
[83]   Engineering the conductive carbon/PEO interface to stabilize solid polymer electrolytes for all-solid-state high voltage LiCoO2 batteries [J].
Liang, Jianneng ;
Sun, Yipeng ;
Zhao, Yang ;
Sun, Qian ;
Luo, Jing ;
Zhao, Feipeng ;
Lin, Xiaoting ;
Li, Xia ;
Li, Ruying ;
Zhang, Li ;
Lu, Shigang ;
Huang, Huan ;
Sun, Xueliang .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (05) :2769-2776
[84]   In Situ Li3PS4 Solid-State Electrolyte Protection Layers for Superior Long-Life and High-Rate Lithium-Metal Anodes [J].
Liang, Jianwen ;
Li, Xiaona ;
Zhao, Yang ;
Goncharova, Lyudmila V. ;
Wang, Gongming ;
Adair, Keegan R. ;
Wang, Changhong ;
Li, Ruying ;
Zhu, Yongchun ;
Qian, Yitai ;
Zhang, Li ;
Yang, Rong ;
Lu, Shigang ;
Sun, Xueliang .
ADVANCED MATERIALS, 2018, 30 (45)
[85]  
Liu D. Y., 2024, Nat. Energy, V9, P559
[86]   Pathways for practical high-energy long-cycling lithium metal batteries [J].
Liu, Jun ;
Bao, Zhenan ;
Cui, Yi ;
Dufek, Eric J. ;
Goodenough, John B. ;
Khalifah, Peter ;
Li, Qiuyan ;
Liaw, Bor Yann ;
Liu, Ping ;
Manthiram, Arumugam ;
Meng, Y. Shirley ;
Subramanian, Venkat R. ;
Toney, Michael F. ;
Viswanathan, Vilayanur V. ;
Whittingham, M. Stanley ;
Xiao, Jie ;
Xu, Wu ;
Yang, Jihui ;
Yang, Xiao-Qing ;
Zhang, Ji-Guang .
NATURE ENERGY, 2019, 4 (03) :180-186
[87]   N, S-Coordinated Co Single Atomic Catalyst Boosting Adsorption and Conversion of Lithium Polysulfides for Lithium-Sulfur Batteries [J].
Liu, Kun ;
Wang, Xinyang ;
Gu, Shuai ;
Yuan, Huimin ;
Jiang, Feng ;
Li, Yingzhi ;
Tan, Wen ;
Long, Qiurong ;
Chen, Jingjing ;
Xu, Zhenghe ;
Lu, Zhouguang .
SMALL, 2022, 18 (46)
[88]   Ultralight Electrolyte for High-Energy Lithium-Sulfur Pouch Cells [J].
Liu, Tao ;
Li, Huajun ;
Yue, Jinming ;
Feng, Jingnan ;
Mao, Minglei ;
Zhu, Xiangzhen ;
Hu, Yong-sheng ;
Li, Hong ;
Huang, Xuejie ;
Chen, Liquan ;
Suo, Liumin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (32) :17547-17555
[89]   A Biomass-Based Integral Approach Enables Li-S Full Pouch Cells with Exceptional Power Density and Energy Density [J].
Liu, Yuping ;
Barnscheidt, Yvo ;
Peng, Manhua ;
Bettels, Frederik ;
Li, Taoran ;
He, Tao ;
Ding, Fei ;
Zhang, Lin .
ADVANCED SCIENCE, 2021, 8 (14)
[90]   Single-atom Catalytic Materials for Lean-electrolyte Ultrastable Lithium-Sulfur Batteries [J].
Lu, Chao ;
Chen, Yan ;
Yang, Yuan ;
Chen, Xi .
NANO LETTERS, 2020, 20 (07) :5522-5530