Toward practical lithium-sulfur batteries

被引:10
作者
Qian, Weiwei [1 ,2 ]
Guo, Yawei [1 ,3 ]
Zuo, Weijing [1 ]
Wu, Xiangkun [1 ]
Zhang, Lan [1 ]
机构
[1] Inst Proc Engn, Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
[2] Henan Univ, Zhengzhou Inst Emerging Ind Technol, Longzihu New Energy Lab, Zhengzhou 450000, Peoples R China
[3] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
基金
国家自然科学基金重大项目; 中国国家自然科学基金;
关键词
LI-S BATTERIES; ENERGY-DENSITY; ORGANOSULFUR COMPOUNDS; CATHODE MATERIAL; ELECTROLYTE; PERFORMANCE; SOLVENT; BINDER; CHEMISTRY; DESIGN;
D O I
10.1039/d4qm00180j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As one of the most promising energy-storage devices, lithium-sulfur batteries (LSBs) have been intensively studied and are currently on the edge of practical applications. Ampere hour (A h) level pouch cells are being prepared; however, they still face multiple challenges such as a low practical energy density, short cycle life, and underlying safety issues. The main reasons for these are due to the contradictions between the battery kinetics and electrolyte/sulfur (E/S) ratio, while the utilization of the metal lithium anode also raises possible dendrite concerns. In this review, we summarize the strategy to realize high-loading cathodes and a lean electrolyte for LSBs. In addition, solid-state LSBs are briefly discussed. Hopefully, this work may promote further advances in practical Li-S batteries. A cathode with an areal capacity of more than 5 mA h cm-2 is crucial for practical Li-S batteries. Besides, reducing the electrolyte weight ratio, in both liquid and solid-state Li-S batteries, is also important.
引用
收藏
页码:2556 / 2577
页数:22
相关论文
共 183 条
[1]   Natural Cocoons Enabling Flexible and Stable Fabric Lithium-Sulfur Full Batteries [J].
An, Yanan ;
Luo, Chao ;
Yao, Dahua ;
Wen, Shujing ;
Zheng, Peitao ;
Chi, Shangsen ;
Yang, Yu ;
Chang, Jian ;
Deng, Yonghong ;
Wang, Chaoyang .
NANO-MICRO LETTERS, 2021, 13 (01)
[2]   New High Donor Electrolyte for Lithium-Sulfur Batteries [J].
Baek, Minsung ;
Shin, Hyuksoo ;
Char, Kookheon ;
Choi, Jang Wook .
ADVANCED MATERIALS, 2020, 32 (52)
[3]   Anode Material Options Toward 500 Wh kg-1 Lithium-Sulfur Batteries [J].
Bi, Chen-Xi ;
Zhao, Meng ;
Hou, Li-Peng ;
Chen, Zi-Xian ;
Zhang, Xue-Qiang ;
Li, Bo-Quan ;
Yuan, Hong ;
Huang, Jia-Qi .
ADVANCED SCIENCE, 2022, 9 (02)
[4]   The role of polysulfide-saturation in electrolytes for high power applications of real world Li-S pouch cells [J].
Boenke, Tom ;
Kirchhoff, Sebastian ;
Reuter, Florian S. ;
Schmidt, Florian ;
Weller, Christine ;
Dorfler, Susanne ;
Schwedtmann, Kai ;
Hartel, Paul ;
Abendroth, Thomas ;
Althues, Holger ;
Weigand, Jan J. ;
Kaskel, Stefan .
NANO RESEARCH, 2023, 16 (06) :8313-8320
[5]   A layer-by-layer supramolecular structure for a sulfur cathode [J].
Bucur, Claudiu B. ;
Muldoon, John ;
Lita, Adrian .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (03) :992-998
[6]   Nitrogen Balance on Ni-N-C Promotor for High-Energy Lithium-Sulfur Pouch Cells [J].
Cao, Xuan ;
Wang, Menglei ;
Li, Yuanli ;
Chen, Le ;
Song, Lixian ;
Cai, Wenlong ;
Zhang, Wei ;
Song, Yingze .
ADVANCED SCIENCE, 2022, 9 (33)
[7]   Constructing mesoporous hollow polysulfane spheres bonded with short-chain sulfurs (Sx, x≤3) as high-performance sulfur cathodes in both ether and ester electrolytes [J].
Chang, Wei ;
Qu, Jin ;
Sui, Yanqiu ;
Ji, Qiu-Yu ;
Zhang, Ting-Ting ;
Zhai, Xian-Zhi ;
Jing, Ya-Qiong ;
Yu, Zhong-Zhen .
ENERGY STORAGE MATERIALS, 2020, 27 :426-434
[8]   Free-Standing Sulfur Cathodes Enabled by a Cationic Polymer for Lean Electrolyte Lithium-Sulfur Batteries [J].
Chen, Hui ;
Zhang, Xipin ;
Li, Senlin ;
Zheng, Yuanhui .
ACS ENERGY LETTERS, 2023, 8 (01) :619-627
[9]   Towards practical Li-S battery with dense and flexible electrode containing lean electrolyte [J].
Chen, Jiahang ;
Zhang, Huiming ;
Yang, Huijun ;
Lei, Jingyu ;
Naveed, Ahmad ;
Yang, Jun ;
Nuli, Yanna ;
Wang, Jiulin .
ENERGY STORAGE MATERIALS, 2020, 27 :307-315
[10]   A Diffusion-Reaction Competition Mechanism to Tailor Lithium Deposition for Lithium-Metal Batteries [J].
Chen, Xiao-Ru ;
Yao, Yu-Xing ;
Yan, Chong ;
Zhang, Rui ;
Cheng, Xin-Bing ;
Zhang, Qiang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (20) :7743-7747