Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β-acetoxycarboxylic acids

被引：1

作者：

Ustyuzhanin, Alexander O. ^{[1
]}

Bityukov, Oleg V. ^{[1
]}

Sokolovskiy, Pavel V. ^{[1
]}

Merkulova, Valentina M. ^{[1
]}

Ilovaisky, Alexey I. ^{[1
]}

He, Liang-Nian ^{[2
,3
]}

Vil', Vera A. ^{[1
]}

Terent'ev, Alexander O. ^{[1
]}

机构：

[1] Russian Acad Sci, N D Zelinsky Inst Organ Chem, 47 Leninsky Prospekt, Moscow 119991, Russia

[2] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China

[3] Nankai Univ, Inst Elemento Organ Chem, Coll Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 62期

基金：

俄罗斯科学基金会;

关键词：

CARBON-DIOXIDE; AROMATIC KETONES; OPERATIVE PARAMETERS; CARBOXYLIC-ACIDS; FACILE SYNTHESIS; REDUCTION; ELECTROCARBOXYLATION;

D O I：

10.1039/d4cc02831g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical hydrocarboxylation of enol acetates with CO2 is developed. The disclosed process provides beta-acetoxycarboxylic acids in 25-66% yields, in contrast to the electrolysis of ketones, silyl enol ethers and vinyl tosylates with CO2, which leads mainly to alcohols.

引用

页码：8099 / 8102

页数：4

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