Skachaite, CaCo(CO3)2, a new member of the dolomite group, from the Brod deposit near Příbram, Czech Republic

被引:0
作者
Sejkora, Jiri [1 ]
Plasil, Jakub [2 ]
Dolnicek, Zdenek [1 ]
Ulmanova, Jana [1 ]
Skoda, Radek [3 ]
机构
[1] Natl Museum, Dept Mineral & Petrol, Cirkusova 1740, Prague 9, Czech Republic
[2] Inst Phys CAS, Slovance 1999-2, Prague 8, Czech Republic
[3] Masaryk Univ, Fac Sci, Dept Geol Sci, Kotlarska 2, Brno 61137, Czech Republic
关键词
skachaite; new mineral; carbonate; cobalt; dolomite group; crystal structure; Brod deposit; P & rcaron; & iacute; bram ore area; Czech Republic; X-RAY; CO; DISTRICT; CARBONATE; PRIBRAM; SERIES; COBALT; PART;
D O I
10.1180/mgm.2024.21
中图分类号
P57 [矿物学];
学科分类号
070901 ;
摘要
Skachaite (IMA2022-143) is a new mineral species discovered in samples from the hydrothermal vein B117, shaft No. 6 at the Brod deposit of the uranium and base-metal Pribram ore district, central Bohemia, Czech Republic. Skachaite is a Co-dominant member of the dolomite group and forms anhedral grains up to 50 mu m in size and as 20-100 mu m thick growth zones in Skachaite-dolomite crystals as a part of carbonate (dolomite, calcite, siderite, spherocobaltite, ankerite, kutnohorite and minrecordite) gangue, associated with native silver, sulfides and arsenides. & Scaron;k & aacute;chaite is pale to bright pink with vitreous lustre. The Mohs hardness is ca. 3 1/2 -4, similar to other members of the dolomite group. The calculated density is 3.140 g.cm(-3). & Scaron;k & aacute;chaite is optically uniaxial (-); the indices of refraction are omega = 1.741(3) and epsilon = 1.535(3). On the basis of electron-microprobe analyses, its empirical formula is Ca-1.00(Co0.45Mg0.38Ca0.08Fe0.05Mn0.03Zn0.01)(Sigma 1.00)(CO3)(2). The ideal formula is CaCo(CO3)(2), which requires (in wt.%) CaO 25.60, CoO 34.21, CO2 40.19, a total of 100.00. Skachaite is trigonal, R3, with unit-cell parameters a = 4.8177(18), c = 16.093(7) & Aring;, V = 323.5(2) & Aring;(3) and Z = 3. The strongest reflections of the calculated powder X-ray diffraction pattern [d, & Aring;, (I-rel, %) hkl] are: 3.704 (13) 102; 2.896 (100) 104; 2.409 (15) 110; 2.019 (17) 202; 1.812 (19) 10; and 1.792 (16) 116. According to the single-crystal X-ray diffraction data (R-1 = 0.0304 for 94 reflections with [I > 3 sigma(I)]), the crystal structure of Skachaite is isotypic with its Mg-analogue, dolomite. The Raman spectrum of Skachaite, as well as the tentative assignment of observed bands, are given in this paper. The mineral is named in honour of Pavel Skacha, a Czech mineralogist and curator of the mineralogical collection of the Mining Museum Pr & iacute;bram, Czech Republic.
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页码:255 / 261
页数:7
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